Xocolatlite, Ca(2)Mn(2)(4+)Te(2)O(12)center dot H(2)O, a new tellurate related to kuranakhite: description and measurement of Te oxidation state by XANES spectroscopy

Pascal Grundler, Joel Brugger, Nicolas Meisser, Stefan Ansermet, Stacey Borg, Barbara Etschmann, Denis Testemale, Trudy Bolin

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Abstract

Xocolatlite, Ca(2)Mn(2)(4+)Te(2)(6+)O(12)center dot H(2)O, is a rare new mineral from the Moctezuma deposit in Sonora, 2 2 Mexico. It occurs as chocolate-brown crystalline crusts on a quartz matrix. Xocolatlite has a copper-brown streak, vitreous luster, and is transparent. Individual crystals show a micaceous habit. Refractive indices were found to be higher than 2.0. Density calculated from the empirical formula is 4.97 g/cm(3), and immersion in Clerici solution indicated a density higher than 4.1 g/cm(3). The mineral is named after the word used by the Aztecs for chocolate, in reference to its brown color and provenance. The crystallographic characteristics of this monoclinic mineral are space group P2, P2/m, or Pm, with the following unit-cell parameters refined from synchrotron X-ray powder diffraction data: a = 10.757(3) angstrom, b = 4.928(3) angstrom, c = 8.942(2) angstrom, beta = 102.39(3)degrees, V = 463.0(3) angstrom(3), and Z = 2. The unavailability of a suitable crystal prevented single-crystal X-ray studies. The strongest 10 lines of the X-ray powder diffraction pattern are [d in angstrom (I) (hkl)]: 3.267(100)(012), 2.52(71)(30 (3) over bar), 4.361(51) (002), 1.762(39)(32 (3) over bar), 4.924 (34)(010), 2.244(32)(31 (3) over bar), 1.455(24)(006), 1.996(21)(014), 1.565(20) (611), and 2.353(18)(41 (1) over bar). XANES Te L(m)-edge spectra of a selection of Te minerals (including xocolatlite) and inorganic compounds showed that the position of the absorption edge can be reliably related to the oxidation state of Te. XANES demonstrated that xocolatlite contains Te(6+) as a tellurate group. Water has been tentatively included in the formula based on IR spectroscopy that indicated the presence of a small amount of water. Raman, IR, XANES, and X-ray diffraction data together with the chemical composition show a similarity of xocolatlite to kuranakhite. A possible series may exist between these two species, xocolatlite being the Ca-rich end-member and kuranakhite the Pb-rich one.
Original languageEnglish
Pages (from-to)1911 - 1920
Number of pages10
JournalAmerican Mineralogist
Volume93
Issue number11-12
DOIs
Publication statusPublished - 2008
Externally publishedYes

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