X-ray crystallographic and theoretical comparison of Ge[2,4,6-(CF3)3C6H2]2 and Ge[N(SiMe3)2]2 as ligands in (Ph3P)2NiGeX2 complexes

J. E. Bender IV; A. J. Shusterman; M. M. Banaszak Holl; J. W. Kampf

X-ray crystallographic and theoretical comparison of Ge[2,4,6-(CF₃)₃C₆H₂]₂ and Ge[N(SiMe₃)₂]₂ as ligands in (Ph₃P)₂NiGeX₂ complexes

J. E. Bender IV, A. J. Shusterman, M. M. Banaszak Holl, J. W. Kampf

Research output: Contribution to journal › Review Article › Research › peer-review

Abstract

A new transition metal germylene complex, (Ph₃P)₂NiGe[2,4,6-(CF₃)₃C ₆H₂]₂ (2), has been synthesized and structurally characterized. The metrical parameters of complex 2 are compared and contrasted with the previously synthesized complexes (Ph₃P)₂NiGe[N(SiMe₃)₂]₂ (3) and (Et₃P)₂PtGe[N(SiMe₃)₂]₂ (1). Nonlocal BP86 density functional calculations support the presence of Ni-Ge d-p π bonding in complexes 2 and 3.

Original language	English
Pages (from-to)	1547-1552
Number of pages	6
Journal	Organometallics
Volume	18
Issue number	8
Publication status	Published - 12 Apr 1999
Externally published	Yes

Cite this

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title = "X-ray crystallographic and theoretical comparison of Ge[2,4,6-(CF3)3C6H2]2 and Ge[N(SiMe3)2]2 as ligands in (Ph3P)2NiGeX2 complexes",

abstract = "A new transition metal germylene complex, (Ph3P)2NiGe[2,4,6-(CF3)3C 6H2]2 (2), has been synthesized and structurally characterized. The metrical parameters of complex 2 are compared and contrasted with the previously synthesized complexes (Ph3P)2NiGe[N(SiMe3)2]2 (3) and (Et3P)2PtGe[N(SiMe3)2]2 (1). Nonlocal BP86 density functional calculations support the presence of Ni-Ge d-p π bonding in complexes 2 and 3.",

author = "{Bender IV}, {J. E.} and Shusterman, {A. J.} and {Banaszak Holl}, {M. M.} and Kampf, {J. W.}",

year = "1999",

month = apr,

day = "12",

language = "English",

volume = "18",

pages = "1547--1552",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - X-ray crystallographic and theoretical comparison of Ge[2,4,6-(CF3)3C6H2]2 and Ge[N(SiMe3)2]2 as ligands in (Ph3P)2NiGeX2 complexes

AU - Bender IV, J. E.

AU - Shusterman, A. J.

AU - Banaszak Holl, M. M.

AU - Kampf, J. W.

PY - 1999/4/12

Y1 - 1999/4/12

N2 - A new transition metal germylene complex, (Ph3P)2NiGe[2,4,6-(CF3)3C 6H2]2 (2), has been synthesized and structurally characterized. The metrical parameters of complex 2 are compared and contrasted with the previously synthesized complexes (Ph3P)2NiGe[N(SiMe3)2]2 (3) and (Et3P)2PtGe[N(SiMe3)2]2 (1). Nonlocal BP86 density functional calculations support the presence of Ni-Ge d-p π bonding in complexes 2 and 3.

AB - A new transition metal germylene complex, (Ph3P)2NiGe[2,4,6-(CF3)3C 6H2]2 (2), has been synthesized and structurally characterized. The metrical parameters of complex 2 are compared and contrasted with the previously synthesized complexes (Ph3P)2NiGe[N(SiMe3)2]2 (3) and (Et3P)2PtGe[N(SiMe3)2]2 (1). Nonlocal BP86 density functional calculations support the presence of Ni-Ge d-p π bonding in complexes 2 and 3.

UR - http://www.scopus.com/inward/record.url?scp=0001692408&partnerID=8YFLogxK

M3 - Review Article

AN - SCOPUS:0001692408

SN - 0276-7333

VL - 18

SP - 1547

EP - 1552

JO - Organometallics

JF - Organometallics

IS - 8

ER -

X-ray crystallographic and theoretical comparison of Ge[2,4,6-(CF3)3C6H2]2 and Ge[N(SiMe3)2]2 as ligands in (Ph3P)2NiGeX2 complexes

Abstract

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X-ray crystallographic and theoretical comparison of Ge[2,4,6-(CF₃)₃C₆H₂]₂ and Ge[N(SiMe₃)₂]₂ as ligands in (Ph₃P)₂NiGeX₂ complexes