X-ray crystallographic and theoretical comparison of Ge[2,4,6-(CF3)3C6H2]2 and Ge[N(SiMe3)2]2 as ligands in (Ph3P)2NiGeX2 complexes

J. E. Bender IV, A. J. Shusterman, M. M. Banaszak Holl, J. W. Kampf

Research output: Contribution to journalReview ArticleResearchpeer-review

29 Citations (Scopus)

Abstract

A new transition metal germylene complex, (Ph3P)2NiGe[2,4,6-(CF3)3C 6H2]2 (2), has been synthesized and structurally characterized. The metrical parameters of complex 2 are compared and contrasted with the previously synthesized complexes (Ph3P)2NiGe[N(SiMe3)2]2 (3) and (Et3P)2PtGe[N(SiMe3)2]2 (1). Nonlocal BP86 density functional calculations support the presence of Ni-Ge d-p π bonding in complexes 2 and 3.

Original languageEnglish
Pages (from-to)1547-1552
Number of pages6
JournalOrganometallics
Volume18
Issue number8
Publication statusPublished - 12 Apr 1999
Externally publishedYes

Cite this

@article{91ca229168d64853baba2869cbdb739a,
title = "X-ray crystallographic and theoretical comparison of Ge[2,4,6-(CF3)3C6H2]2 and Ge[N(SiMe3)2]2 as ligands in (Ph3P)2NiGeX2 complexes",
abstract = "A new transition metal germylene complex, (Ph3P)2NiGe[2,4,6-(CF3)3C 6H2]2 (2), has been synthesized and structurally characterized. The metrical parameters of complex 2 are compared and contrasted with the previously synthesized complexes (Ph3P)2NiGe[N(SiMe3)2]2 (3) and (Et3P)2PtGe[N(SiMe3)2]2 (1). Nonlocal BP86 density functional calculations support the presence of Ni-Ge d-p π bonding in complexes 2 and 3.",
author = "{Bender IV}, {J. E.} and Shusterman, {A. J.} and {Banaszak Holl}, {M. M.} and Kampf, {J. W.}",
year = "1999",
month = "4",
day = "12",
language = "English",
volume = "18",
pages = "1547--1552",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "8",

}

X-ray crystallographic and theoretical comparison of Ge[2,4,6-(CF3)3C6H2]2 and Ge[N(SiMe3)2]2 as ligands in (Ph3P)2NiGeX2 complexes. / Bender IV, J. E.; Shusterman, A. J.; Banaszak Holl, M. M.; Kampf, J. W.

In: Organometallics, Vol. 18, No. 8, 12.04.1999, p. 1547-1552.

Research output: Contribution to journalReview ArticleResearchpeer-review

TY - JOUR

T1 - X-ray crystallographic and theoretical comparison of Ge[2,4,6-(CF3)3C6H2]2 and Ge[N(SiMe3)2]2 as ligands in (Ph3P)2NiGeX2 complexes

AU - Bender IV, J. E.

AU - Shusterman, A. J.

AU - Banaszak Holl, M. M.

AU - Kampf, J. W.

PY - 1999/4/12

Y1 - 1999/4/12

N2 - A new transition metal germylene complex, (Ph3P)2NiGe[2,4,6-(CF3)3C 6H2]2 (2), has been synthesized and structurally characterized. The metrical parameters of complex 2 are compared and contrasted with the previously synthesized complexes (Ph3P)2NiGe[N(SiMe3)2]2 (3) and (Et3P)2PtGe[N(SiMe3)2]2 (1). Nonlocal BP86 density functional calculations support the presence of Ni-Ge d-p π bonding in complexes 2 and 3.

AB - A new transition metal germylene complex, (Ph3P)2NiGe[2,4,6-(CF3)3C 6H2]2 (2), has been synthesized and structurally characterized. The metrical parameters of complex 2 are compared and contrasted with the previously synthesized complexes (Ph3P)2NiGe[N(SiMe3)2]2 (3) and (Et3P)2PtGe[N(SiMe3)2]2 (1). Nonlocal BP86 density functional calculations support the presence of Ni-Ge d-p π bonding in complexes 2 and 3.

UR - http://www.scopus.com/inward/record.url?scp=0001692408&partnerID=8YFLogxK

M3 - Review Article

VL - 18

SP - 1547

EP - 1552

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 8

ER -