X-ray crystal structures of carbonate and hydroxide bridged MnII/MgIIheterobimetallic complexes formed by reduction of CO2or H2O by a Mn0-MgIIbonded compound

Jamie Hicks, Martin Juckel, Cameron Jones

Research output: Contribution to journalArticleResearchpeer-review

2 Citations (Scopus)

Abstract

The previously reported Mn0-MgII bonded heterobimetallic compound [L†Mn-Mg(MesNacnac)] (L† = -N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]-; Mes = mesityl) forms an adduct complex, [L†Mn-Mg(THF)(MesNacnac)], when dissolved in THF. Adventitious water is shown to be reduced by [L†Mn-Mg(MesNacnac)] to give the hydroxide bridged heterobimetallic, [L†Mn(μ-OH)2Mg(MesNacnac)]. The Mn0-MgII bonded heterobimtallic reductively disproportionates CO2, affording the carbonate bridged species, [{L†Mn(μ-CO3)Mg(THF) (MesNacnac)}2], in the presence of THF. The three new compounds have been crystallographically characterized.

Original languageEnglish
Pages (from-to)250-255
Number of pages6
JournalMain Group Metal Chemistry
Volume44
Issue number1
DOIs
Publication statusPublished - 7 Oct 2021

Keywords

  • carbonate
  • heterobimetallic
  • magnesium
  • manganese
  • metal-metal bond

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