TY - JOUR
T1 - Voltammetric studies in "wet" 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl)imide ionic liquid using electrodes with adhered microparticles
AU - Zhao, Shu-Feng
AU - Lu, Jia-Xing
AU - Bond, Alan Maxwell
AU - Zhang, Jie
PY - 2012
Y1 - 2012
N2 - The voltammetry of adhered microparticles provides a convenient method to access water free reversible potentials for water sensitive reduction of benzophenone and 1,4-benzoquinone in wet 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (([Bmpyrd][ENTf2]) (water content similar to 0.13 M) ionic liquid. The outcome that reflects reversible potentials relevant to dry conditions is rationalized in terms of generation of high localized concentrations that significantly exceed the water concentration near the electrode surface.
AB - The voltammetry of adhered microparticles provides a convenient method to access water free reversible potentials for water sensitive reduction of benzophenone and 1,4-benzoquinone in wet 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (([Bmpyrd][ENTf2]) (water content similar to 0.13 M) ionic liquid. The outcome that reflects reversible potentials relevant to dry conditions is rationalized in terms of generation of high localized concentrations that significantly exceed the water concentration near the electrode surface.
UR - http://www.sciencedirect.com.ezproxy.lib.monash.edu.au/science/article/pii/S1388248111005078
U2 - 10.1016/j.elecom.2011.11.034
DO - 10.1016/j.elecom.2011.11.034
M3 - Article
SN - 1388-2481
VL - 16
SP - 14
EP - 18
JO - Electrochemistry Communications
JF - Electrochemistry Communications
IS - 1
ER -