Vibrational spectra of organometallic compounds-III infrared spectra and assignments for bis(pentafluorophenyl)thallium (III) compounds

G. B. Deacon, J. H S Green

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Abstract

Vibrational assignments are given for the infrared absorption frequencies (2000-40 cm-1) of the compounds (C6F5)2TIX (X = F, Cl, or Br). Principal infrared absorption frequencies are listed for forty compounds containing the (C6F5)2Tl group. The number of infrared active absorption bands arising from the 'X-sensitive' mode ν6a1, which involves carbon-thallium stretching, can be correlated with the probable structures of the compounds.

Original languageEnglish
Pages (from-to)1125-1133
Number of pages9
JournalSpectrochimica Acta Part A: Molecular Spectroscopy
Volume24
Issue number8
Publication statusPublished - 1 Aug 1968

Cite this

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abstract = "Vibrational assignments are given for the infrared absorption frequencies (2000-40 cm-1) of the compounds (C6F5)2TIX (X = F, Cl, or Br). Principal infrared absorption frequencies are listed for forty compounds containing the (C6F5)2Tl group. The number of infrared active absorption bands arising from the 'X-sensitive' mode ν6a1, which involves carbon-thallium stretching, can be correlated with the probable structures of the compounds.",
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Vibrational spectra of organometallic compounds-III infrared spectra and assignments for bis(pentafluorophenyl)thallium (III) compounds. / Deacon, G. B.; Green, J. H S.

In: Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 24, No. 8, 01.08.1968, p. 1125-1133.

Research output: Contribution to journalArticleResearchpeer-review

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AB - Vibrational assignments are given for the infrared absorption frequencies (2000-40 cm-1) of the compounds (C6F5)2TIX (X = F, Cl, or Br). Principal infrared absorption frequencies are listed for forty compounds containing the (C6F5)2Tl group. The number of infrared active absorption bands arising from the 'X-sensitive' mode ν6a1, which involves carbon-thallium stretching, can be correlated with the probable structures of the compounds.

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