Vibrational spectra of organometallic compounds-III infrared spectra and assignments for bis(pentafluorophenyl)thallium (III) compounds

G. B. Deacon, J. H S Green

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Abstract

Vibrational assignments are given for the infrared absorption frequencies (2000-40 cm-1) of the compounds (C6F5)2TIX (X = F, Cl, or Br). Principal infrared absorption frequencies are listed for forty compounds containing the (C6F5)2Tl group. The number of infrared active absorption bands arising from the 'X-sensitive' mode ν6a1, which involves carbon-thallium stretching, can be correlated with the probable structures of the compounds.

Original languageEnglish
Pages (from-to)1125-1133
Number of pages9
Journal Spectrochimica Acta Part A: Molecular Spectroscopy
Volume24
Issue number8
Publication statusPublished - 1 Aug 1968

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