TY - JOUR
T1 - Vibrational spectra of ligands and complexes-V. Infrared spectra (380-40 cm-1) of triphenylphosphine complexes of zinc, cadmium and mercury
AU - Deacon, G. B.
AU - Green, J. H S
AU - Harrison, D. J.
PY - 1968/12/1
Y1 - 1968/12/1
N2 - The infrared spectra (380-40 cm-1) of the triphenylphosphine (L) complexes L2MX2 and (LHgX2)2, M = Zn, Cd, or Hg; X = Cl, Br, or I, have been recorded. Assignments are proposed for the M-X stretching, XMX bending, and M-P stretching frequencies of the L2MX2 complexes, and the terminal Hg-X stretching frequencies of the (LHgX2)2 complexes. The M-P stretching frequencies are at ∼160 cm-1 (M = Zn); ∼135 cm-1 (M = Cd); and ∼130 and 105 cm-1 (M = Hg), but they could not be identified for the (LHgX2)2 complexes.
AB - The infrared spectra (380-40 cm-1) of the triphenylphosphine (L) complexes L2MX2 and (LHgX2)2, M = Zn, Cd, or Hg; X = Cl, Br, or I, have been recorded. Assignments are proposed for the M-X stretching, XMX bending, and M-P stretching frequencies of the L2MX2 complexes, and the terminal Hg-X stretching frequencies of the (LHgX2)2 complexes. The M-P stretching frequencies are at ∼160 cm-1 (M = Zn); ∼135 cm-1 (M = Cd); and ∼130 and 105 cm-1 (M = Hg), but they could not be identified for the (LHgX2)2 complexes.
UR - http://www.scopus.com/inward/record.url?scp=0039819653&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0039819653
SN - 0584-8539
VL - 24
SP - 1921
EP - 1928
JO - Spectrochimica Acta Part A: Molecular Spectroscopy
JF - Spectrochimica Acta Part A: Molecular Spectroscopy
IS - 12
ER -