Vibrational spectra of ligands and complexes-IV Infrared spectra of o-phenylenebisdimethylarsine complexes of zinc, cadmium and mercury

G. B. Deacon, J. H S Green

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Abstract

The infrared spectra (3500-500 cm-1) of the o-phenylenebismethylarsine (D) complexes, MD2(ClO4)2 (M = Zn, Cd, or Hg) and (3650-200 cm-1) of MDX2 (M = Zn, Cd, or Hg; X = Cl or Br) and ZnDI2 have been recorded. Assignments of the observed frequencies, including those for the metal-halogen stretching frequencies, are proposed, and are discussed in relation to the structures of the complexes.

Original languageEnglish
Pages (from-to)959-964
Number of pages6
JournalSpectrochimica Acta Part A: Molecular Spectroscopy
Volume24
Issue number8
Publication statusPublished - 1 Aug 1968

Cite this

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title = "Vibrational spectra of ligands and complexes-IV Infrared spectra of o-phenylenebisdimethylarsine complexes of zinc, cadmium and mercury",
abstract = "The infrared spectra (3500-500 cm-1) of the o-phenylenebismethylarsine (D) complexes, MD2(ClO4)2 (M = Zn, Cd, or Hg) and (3650-200 cm-1) of MDX2 (M = Zn, Cd, or Hg; X = Cl or Br) and ZnDI2 have been recorded. Assignments of the observed frequencies, including those for the metal-halogen stretching frequencies, are proposed, and are discussed in relation to the structures of the complexes.",
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Vibrational spectra of ligands and complexes-IV Infrared spectra of o-phenylenebisdimethylarsine complexes of zinc, cadmium and mercury. / Deacon, G. B.; Green, J. H S.

In: Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 24, No. 8, 01.08.1968, p. 959-964.

Research output: Contribution to journalArticleResearchpeer-review

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AU - Deacon, G. B.

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N2 - The infrared spectra (3500-500 cm-1) of the o-phenylenebismethylarsine (D) complexes, MD2(ClO4)2 (M = Zn, Cd, or Hg) and (3650-200 cm-1) of MDX2 (M = Zn, Cd, or Hg; X = Cl or Br) and ZnDI2 have been recorded. Assignments of the observed frequencies, including those for the metal-halogen stretching frequencies, are proposed, and are discussed in relation to the structures of the complexes.

AB - The infrared spectra (3500-500 cm-1) of the o-phenylenebismethylarsine (D) complexes, MD2(ClO4)2 (M = Zn, Cd, or Hg) and (3650-200 cm-1) of MDX2 (M = Zn, Cd, or Hg; X = Cl or Br) and ZnDI2 have been recorded. Assignments of the observed frequencies, including those for the metal-halogen stretching frequencies, are proposed, and are discussed in relation to the structures of the complexes.

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JO - Spectrochimica Acta Part A: Molecular Spectroscopy

JF - Spectrochimica Acta Part A: Molecular Spectroscopy

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