Versatile palladium(II)-catalyzed Suzuki-Miyaura coupling in ethanol with a novel, stabilizing ligand

Jin-Jiao Ning, Jian-Feng Wang, Zhi-Gang Ren, David James Young, Jian-Ping Lang

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    13 Citations (Scopus)

    Abstract

    Suzuki-Miyaura coupling reactions of arylboronic acids with aryl bromides were mediated by PdCl2 and bdppmapy (N,N-bis-(diphenylphosphanylmethyl)-2-aminopyridine) that both stabilizes and solubilizes the catalyst in predominantly ethanol as a solvent. Excellent yields for a wide variety of substrates were obtained under relatively mild conditions in this green solvent.
    Original languageEnglish
    Pages (from-to)4000 - 4006
    Number of pages7
    JournalTetrahedron
    Volume71
    Issue number23
    DOIs
    Publication statusPublished - 2015

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