Variations in yields of di-μ-halogen-bis-[(trihapto-cycloalkenyl) palladium(II)] with ring size. An attempted correlation with the relative ease of hydrogenation of cyclic olefins

H. A. Quinn; W. R. Jackson; J. J. Rooney

doi:10.1039/DT9720000180

Variations in yields of di-μ-halogen-bis-[(trihapto-cycloalkenyl) palladium(II)] with ring size. An attempted correlation with the relative ease of hydrogenation of cyclic olefins

H. A. Quinn, W. R. Jackson, J. J. Rooney

Research output: Contribution to journal › Article › Research › peer-review

4 Citations (Scopus)

Abstract

The yields for the preparation of a series of di-μ-bromo-bis-(trihapto- cycloalkenyl)palladium(II) compounds increase in the sequence C₉ < C₈ < C₆ < C₇. In competitive reactions the reactivity of a series of 3-bromoalkenes with solutions containing palladium(II) increases in the order C₈ < C₆ < C₇. These results parallel the relative ease of hydrogenation of cyclic olefins. The unusual n.m.r. spectrum of di-μ-halogenobis-[(trihapto- cycloheptenyl)palladium(II)] is discussed.

Original language	English
Pages (from-to)	180-181
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/DT9720000180
Publication status	Published - 1 Dec 1972
Externally published	Yes

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title = "Variations in yields of di-μ-halogen-bis-[(trihapto-cycloalkenyl) palladium(II)] with ring size. An attempted correlation with the relative ease of hydrogenation of cyclic olefins",

abstract = "The yields for the preparation of a series of di-μ-bromo-bis-(trihapto- cycloalkenyl)palladium(II) compounds increase in the sequence C9 < C8 < C6 < C7. In competitive reactions the reactivity of a series of 3-bromoalkenes with solutions containing palladium(II) increases in the order C8 < C6 < C7. These results parallel the relative ease of hydrogenation of cyclic olefins. The unusual n.m.r. spectrum of di-μ-halogenobis-[(trihapto- cycloheptenyl)palladium(II)] is discussed.",

author = "Quinn, {H. A.} and Jackson, {W. R.} and Rooney, {J. J.}",

year = "1972",

month = dec,

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doi = "10.1039/DT9720000180",

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pages = "180--181",

journal = " Journal of the Chemical Society - Dalton Transactions",

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publisher = "The Royal Society of Chemistry",

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Variations in yields of di-μ-halogen-bis-[(trihapto-cycloalkenyl) palladium(II)] with ring size. An attempted correlation with the relative ease of hydrogenation of cyclic olefins. / Quinn, H. A.; Jackson, W. R.; Rooney, J. J.
In: Journal of the Chemical Society - Dalton Transactions, No. 2, 01.12.1972, p. 180-181.

Research output: Contribution to journal › Article › Research › peer-review

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T1 - Variations in yields of di-μ-halogen-bis-[(trihapto-cycloalkenyl) palladium(II)] with ring size. An attempted correlation with the relative ease of hydrogenation of cyclic olefins

AU - Quinn, H. A.

AU - Jackson, W. R.

AU - Rooney, J. J.

PY - 1972/12/1

Y1 - 1972/12/1

N2 - The yields for the preparation of a series of di-μ-bromo-bis-(trihapto- cycloalkenyl)palladium(II) compounds increase in the sequence C9 < C8 < C6 < C7. In competitive reactions the reactivity of a series of 3-bromoalkenes with solutions containing palladium(II) increases in the order C8 < C6 < C7. These results parallel the relative ease of hydrogenation of cyclic olefins. The unusual n.m.r. spectrum of di-μ-halogenobis-[(trihapto- cycloheptenyl)palladium(II)] is discussed.

AB - The yields for the preparation of a series of di-μ-bromo-bis-(trihapto- cycloalkenyl)palladium(II) compounds increase in the sequence C9 < C8 < C6 < C7. In competitive reactions the reactivity of a series of 3-bromoalkenes with solutions containing palladium(II) increases in the order C8 < C6 < C7. These results parallel the relative ease of hydrogenation of cyclic olefins. The unusual n.m.r. spectrum of di-μ-halogenobis-[(trihapto- cycloheptenyl)palladium(II)] is discussed.

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DO - 10.1039/DT9720000180

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SN - 1472-7773

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JO - Journal of the Chemical Society - Dalton Transactions

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ER -

Variations in yields of di-μ-halogen-bis-[(trihapto-cycloalkenyl) palladium(II)] with ring size. An attempted correlation with the relative ease of hydrogenation of cyclic olefins

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