Using the emission properties of an intramolecular excimer-forming probe molecule to determine the effect of hydrostatic pressure on local polymer dynamics

Benny D. Freeman; Liliane Bokobza; Philippe Sergot; Lucien Monnerie; F. C. De Schryver

doi:10.1016/0022-2313(91)90118-F

Using the emission properties of an intramolecular excimer-forming probe molecule to determine the effect of hydrostatic pressure on local polymer dynamics

Benny D. Freeman, Liliane Bokobza, Philippe Sergot, Lucien Monnerie, F. C. De Schryver

Research output: Contribution to journal › Article › Research › peer-review

5 Citations (Scopus)

Abstract

The fluorescence lifetime of the intramolecular excimer-forming probe molecule meso-2,4-di(N-carbazolyl) pentane dissolved in cis-polyisoprene and poly(propylene oxide) has been determined as a function of hydrostatic pressure. The rate of the local scale motion of the probe required to form the intramolecular excimer conformation is shown to be controlled by polymer segmental motions connected with the glass-rubber transition phenomenon. The experimental data are compared with the predictions of several free volume-based models of polymer dynamics.

Original language	English
Pages (from-to)	259-264
Number of pages	6
Journal	Journal of Luminescence
Volume	48-49
Issue number	PART 1
DOIs	https://doi.org/10.1016/0022-2313(91)90118-F
Publication status	Published - 1991
Externally published	Yes

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10.1016/0022-2313(91)90118-F

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title = "Using the emission properties of an intramolecular excimer-forming probe molecule to determine the effect of hydrostatic pressure on local polymer dynamics",

abstract = "The fluorescence lifetime of the intramolecular excimer-forming probe molecule meso-2,4-di(N-carbazolyl) pentane dissolved in cis-polyisoprene and poly(propylene oxide) has been determined as a function of hydrostatic pressure. The rate of the local scale motion of the probe required to form the intramolecular excimer conformation is shown to be controlled by polymer segmental motions connected with the glass-rubber transition phenomenon. The experimental data are compared with the predictions of several free volume-based models of polymer dynamics.",

author = "Freeman, {Benny D.} and Liliane Bokobza and Philippe Sergot and Lucien Monnerie and {De Schryver}, {F. C.}",

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Using the emission properties of an intramolecular excimer-forming probe molecule to determine the effect of hydrostatic pressure on local polymer dynamics. / Freeman, Benny D.; Bokobza, Liliane; Sergot, Philippe et al.
In: Journal of Luminescence, Vol. 48-49, No. PART 1, 1991, p. 259-264.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Using the emission properties of an intramolecular excimer-forming probe molecule to determine the effect of hydrostatic pressure on local polymer dynamics

AU - Freeman, Benny D.

AU - Bokobza, Liliane

AU - Sergot, Philippe

AU - Monnerie, Lucien

AU - De Schryver, F. C.

PY - 1991

Y1 - 1991

N2 - The fluorescence lifetime of the intramolecular excimer-forming probe molecule meso-2,4-di(N-carbazolyl) pentane dissolved in cis-polyisoprene and poly(propylene oxide) has been determined as a function of hydrostatic pressure. The rate of the local scale motion of the probe required to form the intramolecular excimer conformation is shown to be controlled by polymer segmental motions connected with the glass-rubber transition phenomenon. The experimental data are compared with the predictions of several free volume-based models of polymer dynamics.

AB - The fluorescence lifetime of the intramolecular excimer-forming probe molecule meso-2,4-di(N-carbazolyl) pentane dissolved in cis-polyisoprene and poly(propylene oxide) has been determined as a function of hydrostatic pressure. The rate of the local scale motion of the probe required to form the intramolecular excimer conformation is shown to be controlled by polymer segmental motions connected with the glass-rubber transition phenomenon. The experimental data are compared with the predictions of several free volume-based models of polymer dynamics.

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U2 - 10.1016/0022-2313(91)90118-F

DO - 10.1016/0022-2313(91)90118-F

M3 - Article

AN - SCOPUS:0025792890

SN - 0022-2313

VL - 48-49

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EP - 264

JO - Journal of Luminescence

JF - Journal of Luminescence

IS - PART 1

ER -

Using the emission properties of an intramolecular excimer-forming probe molecule to determine the effect of hydrostatic pressure on local polymer dynamics

Abstract

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