Unusual alkyl group directing effects during cyclopropane ring hydrogenolysis

M. Naseem Akhtar; W. Roy Jackson; John J. Rooney; Nicolas G. Samman

doi:10.1039/C39740000155

Unusual alkyl group directing effects during cyclopropane ring hydrogenolysis

M. Naseem Akhtar, W. Roy Jackson, John J. Rooney, Nicolas G. Samman

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

2 Citations (Scopus)

Abstract

2-endo-Alkylnorbornanes are the kinetically preferred products of vapour phase hydrogenolysis of 2-methyl- and 2-cyclohexyl-nortricyclenes (1; R = Me and C₆H₁₁) over supported Pt and Pd catalysts, whereas 7-alkylnorbornanes predominate for reactions in acetic acid solutions.

Original language	English
Pages (from-to)	155-156
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39740000155
Publication status	Published - 1 Jan 1974

Access to Document

10.1039/C39740000155

Cite this

@article{50ba1ad47c44483b9777c3f0896e2bde,

title = "Unusual alkyl group directing effects during cyclopropane ring hydrogenolysis",

abstract = "2-endo-Alkylnorbornanes are the kinetically preferred products of vapour phase hydrogenolysis of 2-methyl- and 2-cyclohexyl-nortricyclenes (1; R = Me and C6H11) over supported Pt and Pd catalysts, whereas 7-alkylnorbornanes predominate for reactions in acetic acid solutions.",

author = "Akhtar, {M. Naseem} and Jackson, {W. Roy} and Rooney, {John J.} and Samman, {Nicolas G.}",

year = "1974",

month = jan,

day = "1",

doi = "10.1039/C39740000155",

language = "English",

pages = "155--156",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "The Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - Unusual alkyl group directing effects during cyclopropane ring hydrogenolysis

AU - Akhtar, M. Naseem

AU - Jackson, W. Roy

AU - Rooney, John J.

AU - Samman, Nicolas G.

PY - 1974/1/1

Y1 - 1974/1/1

N2 - 2-endo-Alkylnorbornanes are the kinetically preferred products of vapour phase hydrogenolysis of 2-methyl- and 2-cyclohexyl-nortricyclenes (1; R = Me and C6H11) over supported Pt and Pd catalysts, whereas 7-alkylnorbornanes predominate for reactions in acetic acid solutions.

AB - 2-endo-Alkylnorbornanes are the kinetically preferred products of vapour phase hydrogenolysis of 2-methyl- and 2-cyclohexyl-nortricyclenes (1; R = Me and C6H11) over supported Pt and Pd catalysts, whereas 7-alkylnorbornanes predominate for reactions in acetic acid solutions.

UR - http://www.scopus.com/inward/record.url?scp=37049133162&partnerID=8YFLogxK

U2 - 10.1039/C39740000155

DO - 10.1039/C39740000155

M3 - Article

AN - SCOPUS:37049133162

SN - 0022-4936

SP - 155

EP - 156

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 4

ER -

Unusual alkyl group directing effects during cyclopropane ring hydrogenolysis

Abstract

Access to Document

Other files and links

Cite this