Unusual alkyl group directing effects during cyclopropane ring hydrogenolysis

M. Naseem Akhtar, W. Roy Jackson, John J. Rooney, Nicolas G. Samman

Research output: Contribution to journalArticleResearchpeer-review

2 Citations (Scopus)

Abstract

2-endo-Alkylnorbornanes are the kinetically preferred products of vapour phase hydrogenolysis of 2-methyl- and 2-cyclohexyl-nortricyclenes (1; R = Me and C6H11) over supported Pt and Pd catalysts, whereas 7-alkylnorbornanes predominate for reactions in acetic acid solutions.

Original languageEnglish
Pages (from-to)155-156
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number4
DOIs
Publication statusPublished - 1 Jan 1974

Cite this

Akhtar, M. Naseem ; Jackson, W. Roy ; Rooney, John J. ; Samman, Nicolas G. / Unusual alkyl group directing effects during cyclopropane ring hydrogenolysis. In: Journal of the Chemical Society, Chemical Communications. 1974 ; No. 4. pp. 155-156.
@article{50ba1ad47c44483b9777c3f0896e2bde,
title = "Unusual alkyl group directing effects during cyclopropane ring hydrogenolysis",
abstract = "2-endo-Alkylnorbornanes are the kinetically preferred products of vapour phase hydrogenolysis of 2-methyl- and 2-cyclohexyl-nortricyclenes (1; R = Me and C6H11) over supported Pt and Pd catalysts, whereas 7-alkylnorbornanes predominate for reactions in acetic acid solutions.",
author = "Akhtar, {M. Naseem} and Jackson, {W. Roy} and Rooney, {John J.} and Samman, {Nicolas G.}",
year = "1974",
month = "1",
day = "1",
doi = "10.1039/C39740000155",
language = "English",
pages = "155--156",
journal = "Journal of the Chemical Society - Series Chemical Communications",
issn = "0022-4936",
publisher = "The Royal Society of Chemistry",
number = "4",

}

Unusual alkyl group directing effects during cyclopropane ring hydrogenolysis. / Akhtar, M. Naseem; Jackson, W. Roy; Rooney, John J.; Samman, Nicolas G.

In: Journal of the Chemical Society, Chemical Communications, No. 4, 01.01.1974, p. 155-156.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Unusual alkyl group directing effects during cyclopropane ring hydrogenolysis

AU - Akhtar, M. Naseem

AU - Jackson, W. Roy

AU - Rooney, John J.

AU - Samman, Nicolas G.

PY - 1974/1/1

Y1 - 1974/1/1

N2 - 2-endo-Alkylnorbornanes are the kinetically preferred products of vapour phase hydrogenolysis of 2-methyl- and 2-cyclohexyl-nortricyclenes (1; R = Me and C6H11) over supported Pt and Pd catalysts, whereas 7-alkylnorbornanes predominate for reactions in acetic acid solutions.

AB - 2-endo-Alkylnorbornanes are the kinetically preferred products of vapour phase hydrogenolysis of 2-methyl- and 2-cyclohexyl-nortricyclenes (1; R = Me and C6H11) over supported Pt and Pd catalysts, whereas 7-alkylnorbornanes predominate for reactions in acetic acid solutions.

UR - http://www.scopus.com/inward/record.url?scp=37049133162&partnerID=8YFLogxK

U2 - 10.1039/C39740000155

DO - 10.1039/C39740000155

M3 - Article

SP - 155

EP - 156

JO - Journal of the Chemical Society - Series Chemical Communications

JF - Journal of the Chemical Society - Series Chemical Communications

SN - 0022-4936

IS - 4

ER -