Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species

Chris Ritchie; Eric Burkholder; Paul Kögerler; Leroy Cronin

doi:10.1039/b518316b

Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species

Chris Ritchie, Eric Burkholder, Paul Kögerler, Leroy Cronin

Research output: Contribution to journal › Article › Research › peer-review

80 Citations (Scopus)

Abstract

Unsymmetrical functionalization of a discrete α-{SiW ₁₂O₄₀} Keggin with two heterometallic building blocks, a Cu(ii) dimer and a Cu(ii) monomer, results in the formation of [{Cu ₂(O₂CMe)₂(5,5′-dimethyl-2,2′-bipy) ₂}{Cu(5,5′-dimethyl-2,2′-bipy)₂}SiW ₁₂O₄₀] that displays interesting physical properties.

Original language	English
Pages (from-to)	1712-1714
Number of pages	3
Journal	Dalton Transactions
Volume	6
Issue number	14
DOIs	https://doi.org/10.1039/b518316b
Publication status	Published - 3 Apr 2006
Externally published	Yes

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title = "Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species",

abstract = "Unsymmetrical functionalization of a discrete α-{SiW 12O40} Keggin with two heterometallic building blocks, a Cu(ii) dimer and a Cu(ii) monomer, results in the formation of [{Cu 2(O2CMe)2(5,5′-dimethyl-2,2′-bipy) 2}{Cu(5,5′-dimethyl-2,2′-bipy)2}SiW 12O40] that displays interesting physical properties.",

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AU - Ritchie, Chris

AU - Burkholder, Eric

AU - Kögerler, Paul

AU - Cronin, Leroy

PY - 2006/4/3

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N2 - Unsymmetrical functionalization of a discrete α-{SiW 12O40} Keggin with two heterometallic building blocks, a Cu(ii) dimer and a Cu(ii) monomer, results in the formation of [{Cu 2(O2CMe)2(5,5′-dimethyl-2,2′-bipy) 2}{Cu(5,5′-dimethyl-2,2′-bipy)2}SiW 12O40] that displays interesting physical properties.

AB - Unsymmetrical functionalization of a discrete α-{SiW 12O40} Keggin with two heterometallic building blocks, a Cu(ii) dimer and a Cu(ii) monomer, results in the formation of [{Cu 2(O2CMe)2(5,5′-dimethyl-2,2′-bipy) 2}{Cu(5,5′-dimethyl-2,2′-bipy)2}SiW 12O40] that displays interesting physical properties.

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U2 - 10.1039/b518316b

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Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species

Abstract

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