Unique and contrasting structures of homoleptic lanthanum(iii) and cerium(iii) 3,5-dimethylpyrazolates

Daniel Werner; Uwe Bayer; Nazli E. Rad; Peter C. Junk; Glen B. Deacon; Reiner Anwander

doi:10.1039/c8dt00338f

Unique and contrasting structures of homoleptic lanthanum(iii) and cerium(iii) 3,5-dimethylpyrazolates

Daniel Werner, Uwe Bayer, Nazli E. Rad, Peter C. Junk, Glen B. Deacon, Reiner Anwander

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

17 Citations (Scopus)

Abstract

Homoleptic [La(Me₂pz)₃]_n (Me₂pz = 3,5-dimethylpyrazolato) is a μ-η²:η⁵-Me₂pz coordination polymer with 12-coordinate La atoms in an unusual η⁵:η⁵ Me₂pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce₄(Me₂pz)₁₂] featuring six different Me₂pz coordination modes.

Original language	English
Pages (from-to)	5952-5955
Number of pages	4
Journal	Dalton Transactions
Volume	47
Issue number	17
DOIs	https://doi.org/10.1039/c8dt00338f
Publication status	Published - 1 Jan 2018

Access to Document

10.1039/c8dt00338f

Cite this

@article{8078698b1ee549bf9388867b7e149e1e,

title = "Unique and contrasting structures of homoleptic lanthanum(iii) and cerium(iii) 3,5-dimethylpyrazolates",

abstract = "Homoleptic [La(Me2pz)3]n (Me2pz = 3,5-dimethylpyrazolato) is a μ-η2:η5-Me2pz coordination polymer with 12-coordinate La atoms in an unusual η5:η5 Me2pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce4(Me2pz)12] featuring six different Me2pz coordination modes.",

author = "Daniel Werner and Uwe Bayer and Rad, \{Nazli E.\} and Junk, \{Peter C.\} and Deacon, \{Glen B.\} and Reiner Anwander",

year = "2018",

month = jan,

day = "1",

doi = "10.1039/c8dt00338f",

language = "English",

volume = "47",

pages = "5952--5955",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "The Royal Society of Chemistry",

number = "17",

}

TY - JOUR

T1 - Unique and contrasting structures of homoleptic lanthanum(iii) and cerium(iii) 3,5-dimethylpyrazolates

AU - Werner, Daniel

AU - Bayer, Uwe

AU - Rad, Nazli E.

AU - Junk, Peter C.

AU - Deacon, Glen B.

AU - Anwander, Reiner

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Homoleptic [La(Me2pz)3]n (Me2pz = 3,5-dimethylpyrazolato) is a μ-η2:η5-Me2pz coordination polymer with 12-coordinate La atoms in an unusual η5:η5 Me2pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce4(Me2pz)12] featuring six different Me2pz coordination modes.

AB - Homoleptic [La(Me2pz)3]n (Me2pz = 3,5-dimethylpyrazolato) is a μ-η2:η5-Me2pz coordination polymer with 12-coordinate La atoms in an unusual η5:η5 Me2pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce4(Me2pz)12] featuring six different Me2pz coordination modes.

UR - https://www.scopus.com/pages/publications/85046274319

U2 - 10.1039/c8dt00338f

DO - 10.1039/c8dt00338f

M3 - Article

AN - SCOPUS:85046274319

SN - 1477-9226

VL - 47

SP - 5952

EP - 5955

JO - Dalton Transactions

JF - Dalton Transactions

IS - 17

ER -

Unique and contrasting structures of homoleptic lanthanum(iii) and cerium(iii) 3,5-dimethylpyrazolates

Abstract

Access to Document

Other files and links

Cite this