Unique and contrasting structures of homoleptic lanthanum(iii) and cerium(iii) 3,5-dimethylpyrazolates

Daniel Werner, Uwe Bayer, Nazli E. Rad, Peter C. Junk, Glen B. Deacon, Reiner Anwander

Research output: Contribution to journalArticleResearchpeer-review

7 Citations (Scopus)

Abstract

Homoleptic [La(Me2pz)3]n (Me2pz = 3,5-dimethylpyrazolato) is a μ-η25-Me2pz coordination polymer with 12-coordinate La atoms in an unusual η55 Me2pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce4(Me2pz)12] featuring six different Me2pz coordination modes.

Original languageEnglish
Pages (from-to)5952-5955
Number of pages4
JournalDalton Transactions
Volume47
Issue number17
DOIs
Publication statusPublished - 1 Jan 2018

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