Uncatalyzed oxidation of cyclooctene

Suyog Suresh Mahajan; Man Mohan Sharma; T. Sridhar

doi:10.1021/ie040228l

Uncatalyzed oxidation of cyclooctene

Suyog Suresh Mahajan, Man Mohan Sharma, T. Sridhar

Chemical & Biological Engineering

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7 Citations (Scopus)

Abstract

Cyclooctene was oxidized in the liquid phase by molecular oxygen, and the oxidation kinetics were studied in a batch reactor. Cyclooctene oxide, cyclooctenone, and cyclooctyl hydroperoxide were obtained as oxidation products in the temperature range of 343-373 K. The oxidation was found to be dominated by an addition mechanism, thereby resulting in higher selectivity toward epoxide. The kinetic data were fitted in a rate equation based on autocatalysis by total products. The values of the rate constants and activation energy were determined using the power law model.

Original language	English
Pages (from-to)	1390-1395
Number of pages	6
Journal	Industrial & Engineering Chemistry Research
Volume	44
Issue number	5
DOIs	https://doi.org/10.1021/ie040228l
Publication status	Published - 2 Mar 2005

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abstract = "Cyclooctene was oxidized in the liquid phase by molecular oxygen, and the oxidation kinetics were studied in a batch reactor. Cyclooctene oxide, cyclooctenone, and cyclooctyl hydroperoxide were obtained as oxidation products in the temperature range of 343-373 K. The oxidation was found to be dominated by an addition mechanism, thereby resulting in higher selectivity toward epoxide. The kinetic data were fitted in a rate equation based on autocatalysis by total products. The values of the rate constants and activation energy were determined using the power law model.",

author = "Mahajan, \{Suyog Suresh\} and Sharma, \{Man Mohan\} and T. Sridhar",

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AU - Mahajan, Suyog Suresh

AU - Sharma, Man Mohan

AU - Sridhar, T.

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N2 - Cyclooctene was oxidized in the liquid phase by molecular oxygen, and the oxidation kinetics were studied in a batch reactor. Cyclooctene oxide, cyclooctenone, and cyclooctyl hydroperoxide were obtained as oxidation products in the temperature range of 343-373 K. The oxidation was found to be dominated by an addition mechanism, thereby resulting in higher selectivity toward epoxide. The kinetic data were fitted in a rate equation based on autocatalysis by total products. The values of the rate constants and activation energy were determined using the power law model.

AB - Cyclooctene was oxidized in the liquid phase by molecular oxygen, and the oxidation kinetics were studied in a batch reactor. Cyclooctene oxide, cyclooctenone, and cyclooctyl hydroperoxide were obtained as oxidation products in the temperature range of 343-373 K. The oxidation was found to be dominated by an addition mechanism, thereby resulting in higher selectivity toward epoxide. The kinetic data were fitted in a rate equation based on autocatalysis by total products. The values of the rate constants and activation energy were determined using the power law model.

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DO - 10.1021/ie040228l

M3 - Article

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VL - 44

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EP - 1395

JO - Industrial & Engineering Chemistry Research

JF - Industrial & Engineering Chemistry Research

IS - 5

ER -

Uncatalyzed oxidation of cyclooctene

Abstract

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