四面体磷酸镓和磷酸锗镓构成的新型—维链状分子筛结构

Ya Ming Zhou; Lin Hong Weng; Zhen Xia Chen; Zhi Chen Liu; Jin Yu Sun; Dong Yuan Zhao

四面体磷酸镓和磷酸锗镓构成的新型—维链状分子筛结构

Translated title of the contribution: Two new one-dimensional molecular sieves: Gallium phosphate and germanium gallium phosphate

Ya Ming Zhou, Lin Hong Weng, Zhen Xia Chen, Zhi Chen Liu, Jin Yu Sun, Dong Yuan Zhao

Research output: Contribution to journal › Article › Research › peer-review

Abstract

Solvothermal syntheses and X-ray crystal structures of two phosphates [GaP₂O₇(OH)][NH₃(CH₂) ₃NH₃] (1) and [Ge_0.5GaP_1.5O _6.5(OH)_1.5][NH₃(CH₂) ₃NH₃] (2) are presented. Both structures are built up from GaO₄ and PO₄ tertrahedra or GeO₄, GaO ₄ and PO₄ tertrahedra which form chain along the crystallographic c-axis. These chains are interconnected by 1,3-propanediamine molcules. Crystal data for 1: M_r = 331.82, space group P-1, a = 0.8303(2) nm, b = 0.8614(3) nm, c = 0.8880(2) nm, α = 111.70(3)°, β = 107.59(2)°, γ = 98.39(2)°, V = 0.5382(3) nm³, Z = 1, Mo Kα, λ = 0.071073 nm, R(F) = 5.56%, wR(F²) = 14.36% for 202 parameters and 3136 reflections with I>σ(I). Crystal data for 2; M_r = 358.13, space group P2(1)/c, a = 0.88968(7) nm, b = 1.67562(13) nm, c = 0.83666(7) nm, β = 115.890(2), V = 1.12208(16) nm ³, Z = 4, Mo Kα, R(F) = 4.66%, wR(F²) = 10.10% for 212 parameters and 1612 reflections with I>2σ(I).

Translated title of the contribution	Two new one-dimensional molecular sieves: Gallium phosphate and germanium gallium phosphate
Original language	Chinese
Pages (from-to)	584-590
Number of pages	7
Journal	Acta Chimica Sinica
Volume	61
Issue number	4
Publication status	Published - 1 Dec 2003
Externally published	Yes

Keywords

Gallium phosphate
Germanium gallium phosphate
Microporous material
Solvothermal synthesis
Structure

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@article{73e1e51ea0ed4e999a3d36e4bd6dff31,

title = "四面体磷酸镓和磷酸锗镓构成的新型—维链状分子筛结构",

abstract = "Solvothermal syntheses and X-ray crystal structures of two phosphates [GaP2O7(OH)][NH3(CH2) 3NH3] (1) and [Ge0.5GaP1.5O 6.5(OH)1.5][NH3(CH2) 3NH3] (2) are presented. Both structures are built up from GaO4 and PO4 tertrahedra or GeO4, GaO 4 and PO4 tertrahedra which form chain along the crystallographic c-axis. These chains are interconnected by 1,3-propanediamine molcules. Crystal data for 1: Mr = 331.82, space group P-1, a = 0.8303(2) nm, b = 0.8614(3) nm, c = 0.8880(2) nm, α = 111.70(3)°, β = 107.59(2)°, γ = 98.39(2)°, V = 0.5382(3) nm3, Z = 1, Mo Kα, λ = 0.071073 nm, R(F) = 5.56%, wR(F2) = 14.36% for 202 parameters and 3136 reflections with I>σ(I). Crystal data for 2; Mr = 358.13, space group P2(1)/c, a = 0.88968(7) nm, b = 1.67562(13) nm, c = 0.83666(7) nm, β = 115.890(2), V = 1.12208(16) nm 3, Z = 4, Mo Kα, R(F) = 4.66%, wR(F2) = 10.10% for 212 parameters and 1612 reflections with I>2σ(I).",

keywords = "Gallium phosphate, Germanium gallium phosphate, Microporous material, Solvothermal synthesis, Structure",

author = "Zhou, {Ya Ming} and Weng, {Lin Hong} and Chen, {Zhen Xia} and Liu, {Zhi Chen} and Sun, {Jin Yu} and Zhao, {Dong Yuan}",

year = "2003",

month = dec,

day = "1",

language = "Chinese",

volume = "61",

pages = "584--590",

journal = "Acta Chimica Sinica",

issn = "0567-7351",

publisher = "Shanghai Institute of Organic Chemistry",

number = "4",

}

TY - JOUR

T1 - 四面体磷酸镓和磷酸锗镓构成的新型—维链状分子筛结构

AU - Zhou, Ya Ming

AU - Weng, Lin Hong

AU - Chen, Zhen Xia

AU - Liu, Zhi Chen

AU - Sun, Jin Yu

AU - Zhao, Dong Yuan

PY - 2003/12/1

Y1 - 2003/12/1

N2 - Solvothermal syntheses and X-ray crystal structures of two phosphates [GaP2O7(OH)][NH3(CH2) 3NH3] (1) and [Ge0.5GaP1.5O 6.5(OH)1.5][NH3(CH2) 3NH3] (2) are presented. Both structures are built up from GaO4 and PO4 tertrahedra or GeO4, GaO 4 and PO4 tertrahedra which form chain along the crystallographic c-axis. These chains are interconnected by 1,3-propanediamine molcules. Crystal data for 1: Mr = 331.82, space group P-1, a = 0.8303(2) nm, b = 0.8614(3) nm, c = 0.8880(2) nm, α = 111.70(3)°, β = 107.59(2)°, γ = 98.39(2)°, V = 0.5382(3) nm3, Z = 1, Mo Kα, λ = 0.071073 nm, R(F) = 5.56%, wR(F2) = 14.36% for 202 parameters and 3136 reflections with I>σ(I). Crystal data for 2; Mr = 358.13, space group P2(1)/c, a = 0.88968(7) nm, b = 1.67562(13) nm, c = 0.83666(7) nm, β = 115.890(2), V = 1.12208(16) nm 3, Z = 4, Mo Kα, R(F) = 4.66%, wR(F2) = 10.10% for 212 parameters and 1612 reflections with I>2σ(I).

AB - Solvothermal syntheses and X-ray crystal structures of two phosphates [GaP2O7(OH)][NH3(CH2) 3NH3] (1) and [Ge0.5GaP1.5O 6.5(OH)1.5][NH3(CH2) 3NH3] (2) are presented. Both structures are built up from GaO4 and PO4 tertrahedra or GeO4, GaO 4 and PO4 tertrahedra which form chain along the crystallographic c-axis. These chains are interconnected by 1,3-propanediamine molcules. Crystal data for 1: Mr = 331.82, space group P-1, a = 0.8303(2) nm, b = 0.8614(3) nm, c = 0.8880(2) nm, α = 111.70(3)°, β = 107.59(2)°, γ = 98.39(2)°, V = 0.5382(3) nm3, Z = 1, Mo Kα, λ = 0.071073 nm, R(F) = 5.56%, wR(F2) = 14.36% for 202 parameters and 3136 reflections with I>σ(I). Crystal data for 2; Mr = 358.13, space group P2(1)/c, a = 0.88968(7) nm, b = 1.67562(13) nm, c = 0.83666(7) nm, β = 115.890(2), V = 1.12208(16) nm 3, Z = 4, Mo Kα, R(F) = 4.66%, wR(F2) = 10.10% for 212 parameters and 1612 reflections with I>2σ(I).

KW - Gallium phosphate

KW - Germanium gallium phosphate

KW - Microporous material

KW - Solvothermal synthesis

KW - Structure

UR - http://www.scopus.com/inward/record.url?scp=33750491286&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33750491286

VL - 61

SP - 584

EP - 590

JO - Acta Chimica Sinica

JF - Acta Chimica Sinica

SN - 0567-7351

IS - 4

ER -