Two-coordinate hydrido-germylenes

Terrance Hadlington; Benedikt Schwarze; Ekaterina Pas; Cameron Jones

doi:10.1039/c5cc01314c

Two-coordinate hydrido-germylenes

Terrance Hadlington
, Benedikt Schwarze
, Ekaterina Pas
, Cameron Jones

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

43 Citations (Scopus)

Abstract

The first structurally characterised two-coordinate hydrido-germylenes,:Ge(H)L (L = -N(Ar) Si(OBut3) , Ar = C6H2 C(H)Ph2 2R-2,6,4; R = Pri (tBuOL?), Me (tBuOL*)), have been prepared, and their dimerisation shown to be thermodynamically unfavourable, largely due to the extreme steric bulk of their amide ligands

Original language	English
Pages (from-to)	6854 - 6857
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	31
DOIs	https://doi.org/10.1039/c5cc01314c
Publication status	Published - 2015

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10.1039/c5cc01314c

Cite this

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title = "Two-coordinate hydrido-germylenes",

abstract = "The first structurally characterised two-coordinate hydrido-germylenes,:Ge(H)L (L = -N(Ar) Si(OBut3) , Ar = C6H2 C(H)Ph2 2R-2,6,4; R = Pri (tBuOL?), Me (tBuOL*)), have been prepared, and their dimerisation shown to be thermodynamically unfavourable, largely due to the extreme steric bulk of their amide ligands",

author = "Terrance Hadlington and Benedikt Schwarze and Ekaterina Pas and Cameron Jones",

year = "2015",

doi = "10.1039/c5cc01314c",

language = "English",

volume = "51",

pages = "6854 -- 6857",

journal = "Chemical Communications",

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publisher = "The Royal Society of Chemistry",

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T1 - Two-coordinate hydrido-germylenes

AU - Hadlington, Terrance

AU - Schwarze, Benedikt

AU - Pas, Ekaterina

AU - Jones, Cameron

PY - 2015

Y1 - 2015

N2 - The first structurally characterised two-coordinate hydrido-germylenes,:Ge(H)L (L = -N(Ar) Si(OBut3) , Ar = C6H2 C(H)Ph2 2R-2,6,4; R = Pri (tBuOL?), Me (tBuOL*)), have been prepared, and their dimerisation shown to be thermodynamically unfavourable, largely due to the extreme steric bulk of their amide ligands

AB - The first structurally characterised two-coordinate hydrido-germylenes,:Ge(H)L (L = -N(Ar) Si(OBut3) , Ar = C6H2 C(H)Ph2 2R-2,6,4; R = Pri (tBuOL?), Me (tBuOL*)), have been prepared, and their dimerisation shown to be thermodynamically unfavourable, largely due to the extreme steric bulk of their amide ligands

UR - http://pubs.rsc.org.ezproxy.lib.monash.edu.au/en/content/articlepdf/2015/cc/c5cc01314c?page=search

U2 - 10.1039/c5cc01314c

DO - 10.1039/c5cc01314c

M3 - Article

SN - 1359-7345

VL - 51

SP - 6854

EP - 6857

JO - Chemical Communications

JF - Chemical Communications

IS - 31

ER -

Two-coordinate hydrido-germylenes

Abstract

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Towards ab initio molecular dynamics simulations of proton and electron transfer processes

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Two-coordinate hydrido-germylenes

Abstract

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Towards ab initio molecular dynamics simulations of proton and electron transfer processes

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