Trinodal self-penetrating nets from reactions of 1,4-bis(Alkoxy)-2,5-bis(3,2’:6’,3”-terpyridin-4’-yl)benzene ligands with cobalt(II) thiocyanate

Giacomo Manfroni; Alessandro Prescimone; Stuart R. Batten; Y. Maximilian Klein; Dariusz J. Gawryluk; Edwin C. Constable; Catherine E. Housecroft

doi:10.3390/cryst9100529

Trinodal self-penetrating nets from reactions of 1,4-bis(Alkoxy)-2,5-bis(3,2’:6’,3”-terpyridin-4’-yl)benzene ligands with cobalt(II) thiocyanate

Giacomo Manfroni, Alessandro Prescimone, Stuart R. Batten, Y. Maximilian Klein, Dariusz J. Gawryluk, Edwin C. Constable, Catherine E. Housecroft

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

1 Citation (Scopus)

Abstract

The tetratopic ligands 1,4-bis(2-ethylbutoxy)-2,5-bis(3,2’:6’,3”-terpyridin-4’-yl)benzene (1) and 1,4-bis(3-methylbutoxy)-2,5-bis(3,2’:6’,3”-terpyridin-4’-yl)benzene (2) have been prepared and characterized by¹H and¹³C{¹H} NMR, IR, and absorption spectroscopies and mass spectrometry. Reactions of 1 and 2 with cobalt(II) thiocyanate under conditions of crystal growth at room temperature result in the formation of [{Co(1)(NCS)₂}·MeOH·3CHCl₃]_n and [{Co(2)(NCS)₂}·0.8MeOH·1.8CHCl₃]_n. Single-crystal X-ray diffraction reveals that each crystal lattice consists of a trinodal self-penetrating (6².8⁴)(6⁴.8²)(6⁵.8)₂ net. The nodes are defined by two independent cobalt centres and the centroids of two crystallographically independent ligands which are topologically equivalent.

Original language	English
Article number	529
Number of pages	13
Journal	Crystals
Volume	9
Issue number	10
DOIs	https://doi.org/10.3390/cryst9100529
Publication status	Published - Oct 2019

Keywords

3,2’:6’,3”-terpyridin
Cobalt(II) thiocyanate
Self-penetration
Tetratopic ligand
Three-dimensional network

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10.3390/cryst9100529

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Cite this

@article{9b6302162d9d47aab8f4a9491d43d59f,

title = "Trinodal self-penetrating nets from reactions of 1,4-bis(Alkoxy)-2,5-bis(3,2{\textquoteright}:6{\textquoteright},3”-terpyridin-4{\textquoteright}-yl)benzene ligands with cobalt(II) thiocyanate",

abstract = "The tetratopic ligands 1,4-bis(2-ethylbutoxy)-2,5-bis(3,2{\textquoteright}:6{\textquoteright},3”-terpyridin-4{\textquoteright}-yl)benzene (1) and 1,4-bis(3-methylbutoxy)-2,5-bis(3,2{\textquoteright}:6{\textquoteright},3”-terpyridin-4{\textquoteright}-yl)benzene (2) have been prepared and characterized by1H and13C{1H} NMR, IR, and absorption spectroscopies and mass spectrometry. Reactions of 1 and 2 with cobalt(II) thiocyanate under conditions of crystal growth at room temperature result in the formation of [{Co(1)(NCS)2}·MeOH·3CHCl3]n and [{Co(2)(NCS)2}·0.8MeOH·1.8CHCl3]n. Single-crystal X-ray diffraction reveals that each crystal lattice consists of a trinodal self-penetrating (62.84)(64.82)(65.8)2 net. The nodes are defined by two independent cobalt centres and the centroids of two crystallographically independent ligands which are topologically equivalent.",

keywords = "3,2{\textquoteright}:6{\textquoteright},3”-terpyridin, Cobalt(II) thiocyanate, Self-penetration, Tetratopic ligand, Three-dimensional network",

author = "Giacomo Manfroni and Alessandro Prescimone and Batten, {Stuart R.} and Klein, {Y. Maximilian} and Gawryluk, {Dariusz J.} and Constable, {Edwin C.} and Housecroft, {Catherine E.}",

year = "2019",

month = oct,

doi = "10.3390/cryst9100529",

language = "English",

volume = "9",

journal = "Crystals",

issn = "2073-4352",

publisher = "MDPI AG",

number = "10",

}

Trinodal self-penetrating nets from reactions of 1,4-bis(Alkoxy)-2,5-bis(3,2’:6’,3”-terpyridin-4’-yl)benzene ligands with cobalt(II) thiocyanate. / Manfroni, Giacomo; Prescimone, Alessandro; Batten, Stuart R.; Klein, Y. Maximilian; Gawryluk, Dariusz J.; Constable, Edwin C.; Housecroft, Catherine E.

In: Crystals, Vol. 9, No. 10, 529, 10.2019.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Trinodal self-penetrating nets from reactions of 1,4-bis(Alkoxy)-2,5-bis(3,2’:6’,3”-terpyridin-4’-yl)benzene ligands with cobalt(II) thiocyanate

AU - Manfroni, Giacomo

AU - Prescimone, Alessandro

AU - Batten, Stuart R.

AU - Klein, Y. Maximilian

AU - Gawryluk, Dariusz J.

AU - Constable, Edwin C.

AU - Housecroft, Catherine E.

PY - 2019/10

Y1 - 2019/10

N2 - The tetratopic ligands 1,4-bis(2-ethylbutoxy)-2,5-bis(3,2’:6’,3”-terpyridin-4’-yl)benzene (1) and 1,4-bis(3-methylbutoxy)-2,5-bis(3,2’:6’,3”-terpyridin-4’-yl)benzene (2) have been prepared and characterized by1H and13C{1H} NMR, IR, and absorption spectroscopies and mass spectrometry. Reactions of 1 and 2 with cobalt(II) thiocyanate under conditions of crystal growth at room temperature result in the formation of [{Co(1)(NCS)2}·MeOH·3CHCl3]n and [{Co(2)(NCS)2}·0.8MeOH·1.8CHCl3]n. Single-crystal X-ray diffraction reveals that each crystal lattice consists of a trinodal self-penetrating (62.84)(64.82)(65.8)2 net. The nodes are defined by two independent cobalt centres and the centroids of two crystallographically independent ligands which are topologically equivalent.

AB - The tetratopic ligands 1,4-bis(2-ethylbutoxy)-2,5-bis(3,2’:6’,3”-terpyridin-4’-yl)benzene (1) and 1,4-bis(3-methylbutoxy)-2,5-bis(3,2’:6’,3”-terpyridin-4’-yl)benzene (2) have been prepared and characterized by1H and13C{1H} NMR, IR, and absorption spectroscopies and mass spectrometry. Reactions of 1 and 2 with cobalt(II) thiocyanate under conditions of crystal growth at room temperature result in the formation of [{Co(1)(NCS)2}·MeOH·3CHCl3]n and [{Co(2)(NCS)2}·0.8MeOH·1.8CHCl3]n. Single-crystal X-ray diffraction reveals that each crystal lattice consists of a trinodal self-penetrating (62.84)(64.82)(65.8)2 net. The nodes are defined by two independent cobalt centres and the centroids of two crystallographically independent ligands which are topologically equivalent.

KW - 3,2’:6’,3”-terpyridin

KW - Cobalt(II) thiocyanate

KW - Self-penetration

KW - Tetratopic ligand

KW - Three-dimensional network

UR - http://www.scopus.com/inward/record.url?scp=85073716579&partnerID=8YFLogxK

U2 - 10.3390/cryst9100529

DO - 10.3390/cryst9100529

M3 - Article

AN - SCOPUS:85073716579

VL - 9

JO - Crystals

JF - Crystals

SN - 2073-4352

IS - 10

M1 - 529

ER -