Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation

Ian A. Barker; Andrew P. Dove

doi:10.1039/c2cc38114a

Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation

Ian A. Barker, Andrew P. Dove

Research output: Contribution to journal › Article › Research › peer-review

54 Citations (Scopus)

Abstract

Triarylsulfonium hexafluorophosphate salts were shown to be effective catalysts for the ring-opening polymerisation of various cyclic monomers under UV irradiation. A dual basic/acidic catalytic system demonstrated the potential for UV-triggered formation of poly(δ-valerolactone)-b-poly(l-lactide)-b- poly(δ-valerolactone) in a 'one-pot' reaction.

Original language	English
Pages (from-to)	1205-1207
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	12
DOIs	https://doi.org/10.1039/c2cc38114a
Publication status	Published - 13 Feb 2013
Externally published	Yes

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title = "Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation",

abstract = "Triarylsulfonium hexafluorophosphate salts were shown to be effective catalysts for the ring-opening polymerisation of various cyclic monomers under UV irradiation. A dual basic/acidic catalytic system demonstrated the potential for UV-triggered formation of poly(δ-valerolactone)-b-poly(l-lactide)-b- poly(δ-valerolactone) in a 'one-pot' reaction.",

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AU - Dove, Andrew P.

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N2 - Triarylsulfonium hexafluorophosphate salts were shown to be effective catalysts for the ring-opening polymerisation of various cyclic monomers under UV irradiation. A dual basic/acidic catalytic system demonstrated the potential for UV-triggered formation of poly(δ-valerolactone)-b-poly(l-lactide)-b- poly(δ-valerolactone) in a 'one-pot' reaction.

AB - Triarylsulfonium hexafluorophosphate salts were shown to be effective catalysts for the ring-opening polymerisation of various cyclic monomers under UV irradiation. A dual basic/acidic catalytic system demonstrated the potential for UV-triggered formation of poly(δ-valerolactone)-b-poly(l-lactide)-b- poly(δ-valerolactone) in a 'one-pot' reaction.

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JO - Chemical Communications

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Triarylsulfonium hexafluorophosphate salts as photoactivated acidic catalysts for ring-opening polymerisation

Abstract

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