Trapping CS2 2- and S3 2- between Two Ytterbium Formamidinates

Daniel Werner; Glen B. Deacon; Peter C. Junk

doi:10.1021/acs.inorgchem.8b02820

Trapping CS₂ ^2- and S₃ ^2- between Two Ytterbium Formamidinates

Daniel Werner, Glen B. Deacon, Peter C. Junk

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

22 Citations (Scopus)

Abstract

Treatment of [Yb^II(DippForm)₂(thf)_n] (n = 2 (1aYb), n = 1 (1bYb); DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate), with either excess CS₂ or S₈ gives [Yb^III ₂(DippForm)₄(CS₂)] (3) and [Yb^III ₂(DippForm)₄(S₂)_0.5/(S₃)_0.5] (4) respectively. 3 is a new addition to an exclusive class of compounds containing the CS₂ ^2- dianion, and 4 is the first crystallographically characterized example of a rare-earth trisulfide complex.

Original language	English
Pages (from-to)	1912-1918
Number of pages	7
Journal	Inorganic Chemistry
Volume	58
Issue number	3
DOIs	https://doi.org/10.1021/acs.inorgchem.8b02820
Publication status	Published - 4 Feb 2019

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10.1021/acs.inorgchem.8b02820

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title = "Trapping CS2 2- and S3 2- between Two Ytterbium Formamidinates",

abstract = "Treatment of [YbII(DippForm)2(thf)n] (n = 2 (1aYb), n = 1 (1bYb); DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate), with either excess CS2 or S8 gives [YbIII 2(DippForm)4(CS2)] (3) and [YbIII 2(DippForm)4(S2)0.5/(S3)0.5] (4) respectively. 3 is a new addition to an exclusive class of compounds containing the CS2 2- dianion, and 4 is the first crystallographically characterized example of a rare-earth trisulfide complex.",

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year = "2019",

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journal = "Inorganic Chemistry",

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AU - Werner, Daniel

AU - Deacon, Glen B.

AU - Junk, Peter C.

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N2 - Treatment of [YbII(DippForm)2(thf)n] (n = 2 (1aYb), n = 1 (1bYb); DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate), with either excess CS2 or S8 gives [YbIII 2(DippForm)4(CS2)] (3) and [YbIII 2(DippForm)4(S2)0.5/(S3)0.5] (4) respectively. 3 is a new addition to an exclusive class of compounds containing the CS2 2- dianion, and 4 is the first crystallographically characterized example of a rare-earth trisulfide complex.

AB - Treatment of [YbII(DippForm)2(thf)n] (n = 2 (1aYb), n = 1 (1bYb); DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate), with either excess CS2 or S8 gives [YbIII 2(DippForm)4(CS2)] (3) and [YbIII 2(DippForm)4(S2)0.5/(S3)0.5] (4) respectively. 3 is a new addition to an exclusive class of compounds containing the CS2 2- dianion, and 4 is the first crystallographically characterized example of a rare-earth trisulfide complex.

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SP - 1912

EP - 1918

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3

ER -

Trapping CS₂ ^2- and S₃ ^2- between Two Ytterbium Formamidinates

Abstract

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Reactive metal-organics embracing the rare earth and alkaline earth metals

Australian Synchrotron

Cite this

Trapping CS2 2- and S3 2- between Two Ytterbium Formamidinates

Abstract

Access to Document

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Projects

Reactive metal-organics embracing the rare earth and alkaline earth metals

Equipment

Australian Synchrotron

Cite this

Trapping CS₂ ^2- and S₃ ^2- between Two Ytterbium Formamidinates