Trapping an Unusual Ring-Opened Product of THF within a Lithium Hydrido Aluminate

Matthew J. Evans; Andrea O'Reilly; Mathew D. Anker; Martyn P. Coles

doi:10.1021/acs.organomet.2c00329

Trapping an Unusual Ring-Opened Product of THF within a Lithium Hydrido Aluminate

Matthew J. Evans, Andrea O'Reilly, Mathew D. Anker, Martyn P. Coles

Research output: Contribution to journal › Article › Research › peer-review

3 Citations (Scopus)

Abstract

The reduction of Al(NON^Dipp)I (NON^Dipp= [O(SiMe₂NDipp)₂]^2-, Dipp = 2,6-iPr₂C₆H₃) using lithium metal in THF solvent afforded the but-3-enyl-1-oxido product Al(NON^Dipp)(H)(μ-OCH₂CH₂CH=CH₂)Li(THF)₂. This is the first time that the metalated product of this unusual THF activation pathway has been isolated and structurally characterized.

Original language	English
Pages (from-to)	2657-2661
Number of pages	5
Journal	Organometallics
Volume	41
Issue number	19
DOIs	https://doi.org/10.1021/acs.organomet.2c00329
Publication status	Published - 10 Oct 2022
Externally published	Yes

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title = "Trapping an Unusual Ring-Opened Product of THF within a Lithium Hydrido Aluminate",

abstract = "The reduction of Al(NONDipp)I (NONDipp= [O(SiMe2NDipp)2]2-, Dipp = 2,6-iPr2C6H3) using lithium metal in THF solvent afforded the but-3-enyl-1-oxido product Al(NONDipp)(H)(μ-OCH2CH2CH=CH2)Li(THF)2. This is the first time that the metalated product of this unusual THF activation pathway has been isolated and structurally characterized.",

author = "Evans, {Matthew J.} and Andrea O'Reilly and Anker, {Mathew D.} and Coles, {Martyn P.}",

year = "2022",

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doi = "10.1021/acs.organomet.2c00329",

language = "English",

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AU - Evans, Matthew J.

AU - O'Reilly, Andrea

AU - Anker, Mathew D.

AU - Coles, Martyn P.

PY - 2022/10/10

Y1 - 2022/10/10

N2 - The reduction of Al(NONDipp)I (NONDipp= [O(SiMe2NDipp)2]2-, Dipp = 2,6-iPr2C6H3) using lithium metal in THF solvent afforded the but-3-enyl-1-oxido product Al(NONDipp)(H)(μ-OCH2CH2CH=CH2)Li(THF)2. This is the first time that the metalated product of this unusual THF activation pathway has been isolated and structurally characterized.

AB - The reduction of Al(NONDipp)I (NONDipp= [O(SiMe2NDipp)2]2-, Dipp = 2,6-iPr2C6H3) using lithium metal in THF solvent afforded the but-3-enyl-1-oxido product Al(NONDipp)(H)(μ-OCH2CH2CH=CH2)Li(THF)2. This is the first time that the metalated product of this unusual THF activation pathway has been isolated and structurally characterized.

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U2 - 10.1021/acs.organomet.2c00329

DO - 10.1021/acs.organomet.2c00329

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SP - 2657

EP - 2661

JO - Organometallics

JF - Organometallics

IS - 19

ER -

Trapping an Unusual Ring-Opened Product of THF within a Lithium Hydrido Aluminate

Abstract

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