TY - JOUR
T1 - Transmetallation reactions involving phenylenemercurials
AU - Humphries, R. E.
AU - Al-Jabar, N. A A
AU - Bowen, David
AU - Massey, A. G.
AU - Deacon, G. B.
PY - 1987/1/13
Y1 - 1987/1/13
N2 - When heated with Group V and Group VI elements, the phenylenemercurials (C6H4Hg)3, (C6F4Hg)3 and (C6Cl4Hg)3 form heterocycles of formulae (M2(C6X4)3 and M′2(C6X4)2 where M = As, Sb, Bi and M′ = S, Se, Te. The compounds Te2(C6Cl4)2 and M2(C6Cl4)3 (M = As, Sb, Bi) were also obtained by heating the elements with 1,2-I2C6Cl4, which was prepared by mercuration of 1,2-H2C6Cl4 followed by iododemercuration. Octachlorothianthrene has been obtained by heating sulphur with Te2(C6Cl4)2, C6Cl6 or C6Cl5I, and from the reaction between 1,2-H2C6Cl4, AlCl3, and S2Cl2.
AB - When heated with Group V and Group VI elements, the phenylenemercurials (C6H4Hg)3, (C6F4Hg)3 and (C6Cl4Hg)3 form heterocycles of formulae (M2(C6X4)3 and M′2(C6X4)2 where M = As, Sb, Bi and M′ = S, Se, Te. The compounds Te2(C6Cl4)2 and M2(C6Cl4)3 (M = As, Sb, Bi) were also obtained by heating the elements with 1,2-I2C6Cl4, which was prepared by mercuration of 1,2-H2C6Cl4 followed by iododemercuration. Octachlorothianthrene has been obtained by heating sulphur with Te2(C6Cl4)2, C6Cl6 or C6Cl5I, and from the reaction between 1,2-H2C6Cl4, AlCl3, and S2Cl2.
UR - http://www.scopus.com/inward/record.url?scp=0141765377&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(87)80347-9
DO - 10.1016/0022-328X(87)80347-9
M3 - Article
AN - SCOPUS:0141765377
SN - 0022-328X
VL - 319
SP - 59
EP - 67
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -