Three-dimensional imaging of individual hafnium atoms inside a semiconductor device

The aberration-corrected scanning transmission electron microscope allows probes to be formed with less than 1-?? diameter, providing sufficient sensitivity to observe individual Hf atoms within the SiO2 passivating layer of a HfO2 SiO2 Si alternative gate dielectric stack. Furthermore, the depth resolution is sufficient to localize the atom positions to half-nanometer precision in the third dimension. From a through-focal series of images, we demonstrate a three-dimensional reconstruction of the Hf atom sites, representing a three-dimensional map of potential breakdown sites within the gate dielectric.