TY - JOUR
T1 - Thermal rearrangement of a 1,2-bis(silylene)
T2 - Synthesis and crystal structure of a silyl-silylene
AU - Sidiropoulos, Anastas
AU - Stasch, Andreas
AU - Jones, Cameron
PY - 2019/1
Y1 - 2019/1
N2 - Thermal rearrangement of the 1,2-bis(silylene), [{(4-ButPh)C(NDip)2}Si-]2 (Dip = 2,6-diisopropylphenyl, leads to the silyl-silylene, {(4-ButPh)C(NDip)2}Si-Si(H) {N(Dip)C(=NDip)(4-ButPh-H)}, via an intramolecular C-H activation reaction. The X-ray crystal structure, and limited spectroscopic data, for the compound are reported. The structure of the silyl-silylene incorporates an exocyclic imine fragment, which is unprecedented for this compound class.
AB - Thermal rearrangement of the 1,2-bis(silylene), [{(4-ButPh)C(NDip)2}Si-]2 (Dip = 2,6-diisopropylphenyl, leads to the silyl-silylene, {(4-ButPh)C(NDip)2}Si-Si(H) {N(Dip)C(=NDip)(4-ButPh-H)}, via an intramolecular C-H activation reaction. The X-ray crystal structure, and limited spectroscopic data, for the compound are reported. The structure of the silyl-silylene incorporates an exocyclic imine fragment, which is unprecedented for this compound class.
KW - bis(silylene)
KW - low-oxidation state
KW - silyl-silylene
KW - silylene
KW - X-ray crystallography
UR - http://www.scopus.com/inward/record.url?scp=85069765050&partnerID=8YFLogxK
U2 - 10.1515/mgmc-2019-0013
DO - 10.1515/mgmc-2019-0013
M3 - Article
AN - SCOPUS:85069765050
SN - 0792-1241
VL - 42
SP - 121
EP - 124
JO - Main Group Metal Chemistry
JF - Main Group Metal Chemistry
IS - 1
ER -