TY - JOUR
T1 - Theory of square-wave stripping voltammetry and chronoamperometry of immobilized reactants
AU - Lovrić, M.
AU - Komorsky-Lovrić, Š
AU - Bond, A. M.
PY - 1991/12/10
Y1 - 1991/12/10
N2 - Square-wave stripping voltammograms of redox reactions which involve immobilized reactants and dissolved products are analysed theoretically. The model applies to anodic or cathodic stripping of the material accumulated at an electrode surface by electrodeposition, abrasion, adsorption or the formation of a thin amalgam film. Reversible, quasi-reversible and totally irreversible reactions are considered. The origin of the so-called "quasi-reversible maximum", which could be used for electrode kinetic measurements, is explained using a study of the chronoamperometric properties of these reactions.
AB - Square-wave stripping voltammograms of redox reactions which involve immobilized reactants and dissolved products are analysed theoretically. The model applies to anodic or cathodic stripping of the material accumulated at an electrode surface by electrodeposition, abrasion, adsorption or the formation of a thin amalgam film. Reversible, quasi-reversible and totally irreversible reactions are considered. The origin of the so-called "quasi-reversible maximum", which could be used for electrode kinetic measurements, is explained using a study of the chronoamperometric properties of these reactions.
UR - http://www.scopus.com/inward/record.url?scp=0001791916&partnerID=8YFLogxK
U2 - 10.1016/0022-0728(91)87064-B
DO - 10.1016/0022-0728(91)87064-B
M3 - Article
AN - SCOPUS:0001791916
SN - 0022-0728
VL - 319
SP - 1
EP - 18
JO - Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
JF - Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
IS - 1-2
ER -