The unusual magnetic resonance properties of trigonal prismatic Tc and Re complexes

Simon Drew, John Baldas, John Boas

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    The electron paramagnetic resonance (EPR) spectra of the trigonal prismatic complexes Tc(abt)3, Tc(bdt)3, Re(abt)3 and Re(bdt)3 (abt, O-aminobenzenethiol; bdt, benzene-1,2-dithiol) in dilute frozen solution are interpreted in terms of an axially symmetric spin Hamiltonian, with g values close to two, principal hyperfine couplings of ATc 5-12 x 10-4 cm-1,
    Original languageEnglish
    Pages (from-to)427 - 440
    Number of pages14
    JournalApplied Magnetic Resonance
    Issue number4
    Publication statusPublished - 2011

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