TY - JOUR
T1 - The synthesis and structural characterisation of [IrCl(COD)(PEt 3)n], n = 1 or 2, and orthometallated Vaska's compound, [IrHCl(CO)(PPh3){η2-PPh2(C 6H4)}]
AU - Brym, Markus
AU - Jones, Cameron
PY - 2003/8/1
Y1 - 2003/8/1
N2 - Two iridium(I) complexes, [IrCl(COD)(PEt3)n], n = 1 or 2, have been prepared and structurally characterised. Although [IrCl(COD)(PEt3)] is a known compound the spectroscopic data on both compounds is presented and discussed. In addition, the X-ray crystal structure of the previously described orthometallated isomer of Vaska's compound, [IrHCl(CO)(PPh3){η2-PPh2(C 6H4)}], is reported to show the hydride ligand irons- to the carbonyl ligand.
AB - Two iridium(I) complexes, [IrCl(COD)(PEt3)n], n = 1 or 2, have been prepared and structurally characterised. Although [IrCl(COD)(PEt3)] is a known compound the spectroscopic data on both compounds is presented and discussed. In addition, the X-ray crystal structure of the previously described orthometallated isomer of Vaska's compound, [IrHCl(CO)(PPh3){η2-PPh2(C 6H4)}], is reported to show the hydride ligand irons- to the carbonyl ligand.
UR - http://www.scopus.com/inward/record.url?scp=0041429138&partnerID=8YFLogxK
U2 - 10.1023/A:1025044229274
DO - 10.1023/A:1025044229274
M3 - Article
AN - SCOPUS:0041429138
SN - 0340-4285
VL - 28
SP - 595
EP - 599
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 5
ER -