The synthesis and structural characterisation of a diphosphastibolyl potassium complex, [{[K(DME)][1,4,2-P2SbC2But2]} ], and a novel hetero-cage compound

Cameron Jones, Ryan C. Thomas

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15 Citations (Scopus)

Abstract

The diphosphastibolyl-potassium complex, [{[K(DME)][1,4,2-P2SbC2But2]} ], has been prepared from the reaction of K[Sb(SiMe3)2] with (Me3Si)P=C(But)(OSiMe3). In the solid state it has been shown to exist as an infinite polymer of alternating [K(DME)] and [μ-η55-P2SbC2Bu t2] units. The reaction of two equivalents of this complex with SiMe2Cl2 has afforded a novel hexahetero-cage compound, Me2SiP4SbC4But4H, which has been crystallographically characterised.

Original languageEnglish
Pages (from-to)61-65
Number of pages5
JournalJournal of Organometallic Chemistry
Volume622
Issue number1-2
DOIs
Publication statusPublished - 9 Mar 2001
Externally publishedYes

Keywords

  • Cage compound
  • Crystal structure
  • Diphosphastibolyl
  • Group 15
  • Heterocycle
  • Low coordination

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