The Structure of di-μ-chlorobis[bis(2,3,5,6-tetraflourophenyl)-(triphenylphosphine oxide)thalliium(III)]

Kim Henrick; Mary McPartlin; Ray W. Matthews; Glen B. Deacon; Roderic J. Phillips

doi:10.1016/S0022-328X(00)86071-4

The Structure of di-μ-chlorobis[bis(2,3,5,6-tetraflourophenyl)-(triphenylphosphine oxide)thalliium(III)]

Kim Henrick
, Mary McPartlin
, Ray W. Matthews
, Glen B. Deacon
, Roderic J. Phillips

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

20 Citations (Scopus)

Abstract

An X-ray crytallographic study has shown that the complex (p-HC₆F₄)₂TlCl-(OPPH₃) is dimetric with unsymmetrical chlorine bridging (TlCl 2.541 Å TlCl' 2.936 Å) and five coordinate thallium atoms. The stereochemistry of each thallium is approximately trigonal bipyramidal, the equatorial positions being occupied by two carbon atoms and the more tightly held chlorine. Similar structures are likely for (p-HC₆F₄)₂TlBr(OPPh₃) and (C₆F₅)₂TIX(OPPh₃) (X  Br or Cl).

Original language	English
Pages (from-to)	13-20
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	193
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)86071-4
Publication status	Published - 1 Jan 1980

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title = "The Structure of di-μ-chlorobis[bis(2,3,5,6-tetraflourophenyl)-(triphenylphosphine oxide)thalliium(III)]",

abstract = "An X-ray crytallographic study has shown that the complex (p-HC6F4)2TlCl-(OPPH3) is dimetric with unsymmetrical chlorine bridging (TlCl 2.541 {\AA} TlCl' 2.936 {\AA}) and five coordinate thallium atoms. The stereochemistry of each thallium is approximately trigonal bipyramidal, the equatorial positions being occupied by two carbon atoms and the more tightly held chlorine. Similar structures are likely for (p-HC6F4)2TlBr(OPPh3) and (C6F5)2TIX(OPPh3) (X  Br or Cl).",

author = "Kim Henrick and Mary McPartlin and Matthews, \{Ray W.\} and Deacon, \{Glen B.\} and Phillips, \{Roderic J.\}",

year = "1980",

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doi = "10.1016/S0022-328X(00)86071-4",

language = "English",

volume = "193",

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journal = "Journal of Organometallic Chemistry",

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T1 - The Structure of di-μ-chlorobis[bis(2,3,5,6-tetraflourophenyl)-(triphenylphosphine oxide)thalliium(III)]

AU - Henrick, Kim

AU - McPartlin, Mary

AU - Matthews, Ray W.

AU - Deacon, Glen B.

AU - Phillips, Roderic J.

PY - 1980/1/1

Y1 - 1980/1/1

N2 - An X-ray crytallographic study has shown that the complex (p-HC6F4)2TlCl-(OPPH3) is dimetric with unsymmetrical chlorine bridging (TlCl 2.541 Å TlCl' 2.936 Å) and five coordinate thallium atoms. The stereochemistry of each thallium is approximately trigonal bipyramidal, the equatorial positions being occupied by two carbon atoms and the more tightly held chlorine. Similar structures are likely for (p-HC6F4)2TlBr(OPPh3) and (C6F5)2TIX(OPPh3) (X  Br or Cl).

AB - An X-ray crytallographic study has shown that the complex (p-HC6F4)2TlCl-(OPPH3) is dimetric with unsymmetrical chlorine bridging (TlCl 2.541 Å TlCl' 2.936 Å) and five coordinate thallium atoms. The stereochemistry of each thallium is approximately trigonal bipyramidal, the equatorial positions being occupied by two carbon atoms and the more tightly held chlorine. Similar structures are likely for (p-HC6F4)2TlBr(OPPh3) and (C6F5)2TIX(OPPh3) (X  Br or Cl).

UR - https://www.scopus.com/pages/publications/85025785534

U2 - 10.1016/S0022-328X(00)86071-4

DO - 10.1016/S0022-328X(00)86071-4

M3 - Article

AN - SCOPUS:85025785534

SN - 0022-328X

VL - 193

SP - 13

EP - 20

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

The Structure of di-μ-chlorobis[bis(2,3,5,6-tetraflourophenyl)-(triphenylphosphine oxide)thalliium(III)]

Abstract

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