The structural characterization of YbI2(DME)3

David E. Hibbs; Cameron Jones; Anne F. Richards

doi:10.1023/A:1009557708382

The structural characterization of YbI₂(DME)₃

David E. Hibbs, Cameron Jones, Anne F. Richards

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

8 Citations (Scopus)

Abstract

The preparation and structural characterization of [YbI₂(DME)₂] are reported. The complex crystallizes in the triclinic space group P 1̄: a = 13.0094 (10), b = 14.504(3), c = 14.668 (3) Å, α = 115.281(10) β= 106.74(2), γ = 105.97(2)°. The metal center of the complex exhibits a distorted pentagonal bipyramidal coordination geometry which involves a rare example of a monodentate DME ligand.

Original language	English
Pages (from-to)	1107-1110
Number of pages	4
Journal	Journal of Chemical Crystallography
Volume	29
Issue number	10
DOIs	https://doi.org/10.1023/A:1009557708382
Publication status	Published - 1 Jan 1999

Keywords

Coordination complex
Crystal structure
Lanthanide
Ytterbium

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10.1023/A:1009557708382

Cite this

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title = "The structural characterization of YbI2(DME)3",

abstract = "The preparation and structural characterization of [YbI2(DME)2] are reported. The complex crystallizes in the triclinic space group P {\=1}: a = 13.0094 (10), b = 14.504(3), c = 14.668 (3) {\AA}, α = 115.281(10) β= 106.74(2), γ = 105.97(2)°. The metal center of the complex exhibits a distorted pentagonal bipyramidal coordination geometry which involves a rare example of a monodentate DME ligand.",

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T1 - The structural characterization of YbI2(DME)3

AU - Hibbs, David E.

AU - Jones, Cameron

AU - Richards, Anne F.

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N2 - The preparation and structural characterization of [YbI2(DME)2] are reported. The complex crystallizes in the triclinic space group P 1̄: a = 13.0094 (10), b = 14.504(3), c = 14.668 (3) Å, α = 115.281(10) β= 106.74(2), γ = 105.97(2)°. The metal center of the complex exhibits a distorted pentagonal bipyramidal coordination geometry which involves a rare example of a monodentate DME ligand.

AB - The preparation and structural characterization of [YbI2(DME)2] are reported. The complex crystallizes in the triclinic space group P 1̄: a = 13.0094 (10), b = 14.504(3), c = 14.668 (3) Å, α = 115.281(10) β= 106.74(2), γ = 105.97(2)°. The metal center of the complex exhibits a distorted pentagonal bipyramidal coordination geometry which involves a rare example of a monodentate DME ligand.

KW - Coordination complex

KW - Crystal structure

KW - Lanthanide

KW - Ytterbium

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