The stereochemistry of organometallic compounds. XXXIV: Regioselection in the hydroformylation of silylalkenes

M. Michael Doyle; W. Roy Jackson; Patrick Perlmutter

doi:10.1071/CH9891907

The stereochemistry of organometallic compounds. XXXIV: Regioselection in the hydroformylation of silylalkenes

M. Michael Doyle, W. Roy Jackson, Patrick Perlmutter

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

22 Citations (Scopus)

Abstract

The regiochemistry of hydroformylation of alkenes can be controlled by the use of bulky silyl groups attached to the alkene. Use of the t-butyldiphenylsilyl group leads to almost total regiocontrol and the method has been applied to the synthesis of aldols.

Original language	English
Pages (from-to)	1907-1918
Number of pages	12
Journal	Australian Journal of Chemistry
Volume	42
Issue number	11
DOIs	https://doi.org/10.1071/CH9891907
Publication status	Published - 1 Jan 1989

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10.1071/CH9891907

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Cite this

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title = "The stereochemistry of organometallic compounds. XXXIV: Regioselection in the hydroformylation of silylalkenes",

abstract = "The regiochemistry of hydroformylation of alkenes can be controlled by the use of bulky silyl groups attached to the alkene. Use of the t-butyldiphenylsilyl group leads to almost total regiocontrol and the method has been applied to the synthesis of aldols.",

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AB - The regiochemistry of hydroformylation of alkenes can be controlled by the use of bulky silyl groups attached to the alkene. Use of the t-butyldiphenylsilyl group leads to almost total regiocontrol and the method has been applied to the synthesis of aldols.

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