The stereochemistry of organometallic compounds. XXVIII the nickel-catalysed addition of hydrogen cyanide to aliphatic dienes

Eva M. Campi; Patricia S. Elmes; W. Roy Jackson; Craig G. Lovel; Michael K.S. Probert

doi:10.1071/CH9871053

The stereochemistry of organometallic compounds. XXVIII the nickel-catalysed addition of hydrogen cyanide to aliphatic dienes

Eva M. Campi
, Patricia S. Elmes
, W. Roy Jackson
, Craig G. Lovel
, Michael K.S. Probert

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

14 Citations (Scopus)

Abstract

Reaction of hydrogen cyanide with a wide range of aliphatic dienes in the presence of nickel(0) catalysts leads to rearrangement of the diene and formation of β, γ-unsaturated nitriles in moderate to very high yields. The mechanism of reaction is discussed in terms of π-allyl-nickel intermediates.

Original language	English
Pages (from-to)	1053-1061
Number of pages	9
Journal	Australian Journal of Chemistry
Volume	40
Issue number	6
DOIs	https://doi.org/10.1071/CH9871053
Publication status	Published - 1 Jan 1987

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title = "The stereochemistry of organometallic compounds. XXVIII the nickel-catalysed addition of hydrogen cyanide to aliphatic dienes",

abstract = "Reaction of hydrogen cyanide with a wide range of aliphatic dienes in the presence of nickel(0) catalysts leads to rearrangement of the diene and formation of β, γ-unsaturated nitriles in moderate to very high yields. The mechanism of reaction is discussed in terms of π-allyl-nickel intermediates.",

author = "Campi, \{Eva M.\} and Elmes, \{Patricia S.\} and \{Roy Jackson\}, W. and Lovel, \{Craig G.\} and Probert, \{Michael K.S.\}",

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AU - Campi, Eva M.

AU - Elmes, Patricia S.

AU - Roy Jackson, W.

AU - Lovel, Craig G.

AU - Probert, Michael K.S.

PY - 1987/1/1

Y1 - 1987/1/1

N2 - Reaction of hydrogen cyanide with a wide range of aliphatic dienes in the presence of nickel(0) catalysts leads to rearrangement of the diene and formation of β, γ-unsaturated nitriles in moderate to very high yields. The mechanism of reaction is discussed in terms of π-allyl-nickel intermediates.

AB - Reaction of hydrogen cyanide with a wide range of aliphatic dienes in the presence of nickel(0) catalysts leads to rearrangement of the diene and formation of β, γ-unsaturated nitriles in moderate to very high yields. The mechanism of reaction is discussed in terms of π-allyl-nickel intermediates.

UR - https://www.scopus.com/pages/publications/84970549087

U2 - 10.1071/CH9871053

DO - 10.1071/CH9871053

M3 - Article

AN - SCOPUS:84970549087

SN - 0004-9425

VL - 40

SP - 1053

EP - 1061

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 6

ER -

The stereochemistry of organometallic compounds. XXVIII the nickel-catalysed addition of hydrogen cyanide to aliphatic dienes

Abstract

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