The stereochemistry of organometallic compounds. XX the stereochemistry of formation of (1-3-η)-PdCl complexes from deutero-substituted 1-acety1-4-t-butylcyclohex-1-enes

Bruce A.W. Coller, W. Roy Jackson, Anna Stragalinou, Jürgen U.G. Strauss

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Abstract

The preparation and assignment of stereochemistry of some deutero-substituted l-acetyl-4-t-butyl- cyclohex-l-enes is described. The formation of (l-3-η)-PdCl complexes from these compounds is accompanied by a non-stereoselective loss of H and D, in agreement with a mechanism of formation which involves an initial palladium-assisted enolization of the ketone.

Original languageEnglish
Pages (from-to)171-180
Number of pages10
JournalAustralian Journal of Chemistry
Volume34
Issue number1
DOIs
Publication statusPublished - 1 Jan 1981

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