Abstract
Reactions of π-allylpalladium compounds with sodium acetylacetonate, sodium malononitrile, and sodium ethylacetoacetate in dimethyl sulfoxide solution give diallyl substitution products. Reaction of the acetylacetonate complexes with carbon monoxide in benzene give mono-allyl substitution products. Application of these reactions to the π-allyl complexes from 1-acetyl-4-t-butylcyclohex-1-ene and from 3-oxo 4-ene steroids in an attempt to examine the stereochemistry of ligand transfer gave no substitution products.
Original language | English |
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Pages (from-to) | 1073-1079 |
Number of pages | 7 |
Journal | Australian Journal of Chemistry |
Volume | 31 |
Issue number | 5 |
DOIs | |
Publication status | Published - 1 Jan 1978 |