The stereochemistry of organometallic compounds. XV* Reactions of the allylpalladium complexes of α,β-unsaturated ketones and esters with nucleophiles

W. Roy Jackson, Jürgen U. Strauss

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23 Citations (Scopus)

Abstract

Reactions of π-allylpalladium complexes of α,β-unsaturated ketones and esters with nucleophiles occur regioselectively at the γ-carbon atom to give high yields of γ-functionalized products. The E/Z-stereochemistry of the products is discussed in relation to the syn/anti-stereochemistry of the π-allylpalladium compounds and the reactivity of the latter compounds is discussed in terms of their 1H and 13C N.M.R. spectra.

Original languageEnglish
Pages (from-to)553-562
Number of pages10
JournalAustralian Journal of Chemistry
Volume30
Issue number3
DOIs
Publication statusPublished - 1 Jan 1977

Cite this

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abstract = "Reactions of π-allylpalladium complexes of α,β-unsaturated ketones and esters with nucleophiles occur regioselectively at the γ-carbon atom to give high yields of γ-functionalized products. The E/Z-stereochemistry of the products is discussed in relation to the syn/anti-stereochemistry of the π-allylpalladium compounds and the reactivity of the latter compounds is discussed in terms of their 1H and 13C N.M.R. spectra.",
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The stereochemistry of organometallic compounds. XV* Reactions of the allylpalladium complexes of α,β-unsaturated ketones and esters with nucleophiles. / Roy Jackson, W.; Strauss, Jürgen U.

In: Australian Journal of Chemistry, Vol. 30, No. 3, 01.01.1977, p. 553-562.

Research output: Contribution to journalArticleResearchpeer-review

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