The stereochemistry of organometallic compounds. XIV. trans-Effects in the 13C N.M.R. spectra of Dicarbonyltriphenyl-phosphine- and arsine-(arene)chromium compounds

W. Roy Jackson, Christopher F. Pincombe, Ian D. Rae, Douglas Rash, Barbara Wilkinson

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17 Citations (Scopus)

Abstract

The 13C chemical shifts of some triphenyl-phosphine and arsine dicarbonyl(arene)chromiums are reported. The shifts are discussed in terms of a deshielding effect on the arene ring carbons trans to the Group 5 atom in the preferred conformations of these molecules.

Original languageEnglish
Pages (from-to)2431-2436
Number of pages6
JournalAustralian Journal of Chemistry
Volume29
Issue number11
DOIs
Publication statusPublished - 1976

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