The stereochemistry of organometallic compounds. XIII: The 13C N.M.R. spectra of some tricarbonyl(arene)chromium compounds

W. Roy Jackson; Christopher F. Pincombe; Ian D. Rae; Sirinant Thapebinkarn

doi:10.1071/CH9751535

The stereochemistry of organometallic compounds. XIII: The ¹³C N.M.R. spectra of some tricarbonyl(arene)chromium compounds

W. Roy Jackson, Christopher F. Pincombe, Ian D. Rae, Sirinant Thapebinkarn

School of Chemistry

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Abstract

The ¹³C n.m.r, spectra of a series of tricarbonyl(arene)chromiums have been determined. The spectra are interpreted in terms of electronic effects of the substituent together with effects arising from conformational preferences of the tricarbonylchromium residue. No evidence for kinetic restriction of rotation could be found for any of the complexes at temperatures greater than -60°.

Original language	English
Pages (from-to)	1535-1539
Number of pages	5
Journal	Australian Journal of Chemistry
Volume	28
Issue number	7
DOIs	https://doi.org/10.1071/CH9751535
Publication status	Published - 1 Jan 1975

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abstract = "The 13C n.m.r, spectra of a series of tricarbonyl(arene)chromiums have been determined. The spectra are interpreted in terms of electronic effects of the substituent together with effects arising from conformational preferences of the tricarbonylchromium residue. No evidence for kinetic restriction of rotation could be found for any of the complexes at temperatures greater than -60°.",

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AB - The 13C n.m.r, spectra of a series of tricarbonyl(arene)chromiums have been determined. The spectra are interpreted in terms of electronic effects of the substituent together with effects arising from conformational preferences of the tricarbonylchromium residue. No evidence for kinetic restriction of rotation could be found for any of the complexes at temperatures greater than -60°.

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The stereochemistry of organometallic compounds. XIII: The 13C N.M.R. spectra of some tricarbonyl(arene)chromium compounds

Abstract

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The stereochemistry of organometallic compounds. XIII: The ¹³C N.M.R. spectra of some tricarbonyl(arene)chromium compounds