The rhodium-catalysed synthesis of pyrrolidinone-substituted (trialkylsilyloxy)acrylic esters

Daniel Priebbenow, Carsten Bolm

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21 Citations (Scopus)

Abstract

A method for the preparation of novel pyrrolidine substituted (trialkylsilyloxy)acrylic esters has been developed. The protocol involves a rhodium-catalysed O-insertion/rearrangement reaction between N-functionalised 2-pyrrolidinones and a-silyl a-diazoacetates to form the corresponding acrylic esters in moderate to high yields.
Original languageEnglish
Pages (from-to)10318 - 10322
Number of pages5
JournalRSC Advances
Volume3
Issue number26
DOIs
Publication statusPublished - 2013
Externally publishedYes

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