The reaction of ‘GaI’ with a 1,3-diyne: synthesis, characterisation and reactivity of a novel C-C coupled ene-diyne-bis(gem-organodigallium(iii)) complex

Robert J. Baker; Cameron Jones

doi:10.1039/b210868m

The reaction of ‘GaI’ with a 1,3-diyne: synthesis, characterisation and reactivity of a novel C-C coupled ene-diyne-bis(gem-organodigallium(iii)) complex

Robert J. Baker, Cameron Jones

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

14 Citations (Scopus)

Abstract

Treatment of ‘GaI’ with a 1,3-diyne, Me₃SiC≡CC≡CSiMe₃, leads to C-C coupling reactions and the isolation of the novel organogallium species, [Ga₄I₈(C₈(SiMe₃)₄)], as two isomeric forms; their X-ray crystal structures show them to contain the first structurally authenticated gem-organodigallium fragments and to exhibit rare examples of Ga-alkyne π-interactions.

Original language	English
Pages (from-to)	390-391
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	3
DOIs	https://doi.org/10.1039/b210868m
Publication status	Published - 1 Jan 2003

Access to Document

10.1039/b210868m

Cite this

@article{fea6411b02644ba58affb56070324069,

title = "The reaction of {\textquoteleft}GaI{\textquoteright} with a 1,3-diyne: synthesis, characterisation and reactivity of a novel C-C coupled ene-diyne-bis(gem-organodigallium(iii)) complex",

abstract = "Treatment of {\textquoteleft}GaI{\textquoteright} with a 1,3-diyne, Me3SiC≡CC≡CSiMe3, leads to C-C coupling reactions and the isolation of the novel organogallium species, [Ga4I8(C8(SiMe3)4)], as two isomeric forms; their X-ray crystal structures show them to contain the first structurally authenticated gem-organodigallium fragments and to exhibit rare examples of Ga-alkyne π-interactions.",

author = "Baker, {Robert J.} and Cameron Jones",

year = "2003",

month = jan,

day = "1",

doi = "10.1039/b210868m",

language = "English",

volume = "3",

pages = "390--391",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "3",

}

TY - JOUR

T1 - The reaction of ‘GaI’ with a 1,3-diyne

T2 - synthesis, characterisation and reactivity of a novel C-C coupled ene-diyne-bis(gem-organodigallium(iii)) complex

AU - Baker, Robert J.

AU - Jones, Cameron

PY - 2003/1/1

Y1 - 2003/1/1

N2 - Treatment of ‘GaI’ with a 1,3-diyne, Me3SiC≡CC≡CSiMe3, leads to C-C coupling reactions and the isolation of the novel organogallium species, [Ga4I8(C8(SiMe3)4)], as two isomeric forms; their X-ray crystal structures show them to contain the first structurally authenticated gem-organodigallium fragments and to exhibit rare examples of Ga-alkyne π-interactions.

AB - Treatment of ‘GaI’ with a 1,3-diyne, Me3SiC≡CC≡CSiMe3, leads to C-C coupling reactions and the isolation of the novel organogallium species, [Ga4I8(C8(SiMe3)4)], as two isomeric forms; their X-ray crystal structures show them to contain the first structurally authenticated gem-organodigallium fragments and to exhibit rare examples of Ga-alkyne π-interactions.

UR - http://www.scopus.com/inward/record.url?scp=0037423441&partnerID=8YFLogxK

U2 - 10.1039/b210868m

DO - 10.1039/b210868m

M3 - Article

C2 - 12613627

AN - SCOPUS:0037423441

SN - 1359-7345

VL - 3

SP - 390

EP - 391

JO - Chemical Communications

JF - Chemical Communications

IS - 3

ER -

The reaction of ‘GaI’ with a 1,3-diyne: synthesis, characterisation and reactivity of a novel C-C coupled ene-diyne-bis(gem-organodigallium(iii)) complex

Abstract

Access to Document

Other files and links

Cite this