The preparation and crystal structure of bis(cyclopentadienyl)(2,6-diphenylphenoxo)bis(tetrahydrofuran)neodymium(III); an unexpected example of formal nine coordination

G. B. Deacon; S. Nickel; E. R T Tiekink

doi:10.1016/0022-328X(91)86156-K

The preparation and crystal structure of bis(cyclopentadienyl)(2,6-diphenylphenoxo)bis(tetrahydrofuran)neodymium(III); an unexpected example of formal nine coordination

G. B. Deacon, S. Nickel, E. R T Tiekink

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

15 Citations (Scopus)

Abstract

Reaction of NdCP₃ (CP=cyclopentadienyl) with an equimolar amount of 2,6-diphenylphenol (HOdpp) in tetrahydrofuran (thf) yields the formally ninecoordinate [NdCp₂(Odpp)(thf)₂]. The crystal structure shows a distorted trigonal bipyramidal arrangement of oxygen donor atoms and cyclopentadienyl ring centroids, with the thf oxygens in the axial positions and a twofold axis along NdOdpp bond.

Original language	English
Pages (from-to)	1-4
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	409
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(91)86156-K
Publication status	Published - 28 May 1991

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title = "The preparation and crystal structure of bis(cyclopentadienyl)(2,6-diphenylphenoxo)bis(tetrahydrofuran)neodymium(III); an unexpected example of formal nine coordination",

abstract = "Reaction of NdCP3 (CP=cyclopentadienyl) with an equimolar amount of 2,6-diphenylphenol (HOdpp) in tetrahydrofuran (thf) yields the formally ninecoordinate [NdCp2(Odpp)(thf)2]. The crystal structure shows a distorted trigonal bipyramidal arrangement of oxygen donor atoms and cyclopentadienyl ring centroids, with the thf oxygens in the axial positions and a twofold axis along NdOdpp bond. ",

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The preparation and crystal structure of bis(cyclopentadienyl)(2,6-diphenylphenoxo)bis(tetrahydrofuran)neodymium(III); an unexpected example of formal nine coordination. / Deacon, G. B.; Nickel, S.; Tiekink, E. R T.
In: Journal of Organometallic Chemistry, Vol. 409, No. 1-2, 28.05.1991, p. 1-4.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - The preparation and crystal structure of bis(cyclopentadienyl)(2,6-diphenylphenoxo)bis(tetrahydrofuran)neodymium(III); an unexpected example of formal nine coordination

AU - Deacon, G. B.

AU - Nickel, S.

AU - Tiekink, E. R T

PY - 1991/5/28

Y1 - 1991/5/28

N2 - Reaction of NdCP3 (CP=cyclopentadienyl) with an equimolar amount of 2,6-diphenylphenol (HOdpp) in tetrahydrofuran (thf) yields the formally ninecoordinate [NdCp2(Odpp)(thf)2]. The crystal structure shows a distorted trigonal bipyramidal arrangement of oxygen donor atoms and cyclopentadienyl ring centroids, with the thf oxygens in the axial positions and a twofold axis along NdOdpp bond.

AB - Reaction of NdCP3 (CP=cyclopentadienyl) with an equimolar amount of 2,6-diphenylphenol (HOdpp) in tetrahydrofuran (thf) yields the formally ninecoordinate [NdCp2(Odpp)(thf)2]. The crystal structure shows a distorted trigonal bipyramidal arrangement of oxygen donor atoms and cyclopentadienyl ring centroids, with the thf oxygens in the axial positions and a twofold axis along NdOdpp bond.

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ER -

The preparation and crystal structure of bis(cyclopentadienyl)(2,6-diphenylphenoxo)bis(tetrahydrofuran)neodymium(III); an unexpected example of formal nine coordination

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