The points of contact between poly(methyl methacrylate) and absorbed water as indicated by PE/MAS 13C NMR

P. E M Alien, S. Hagias, G. P. Simon, E. H. Williams, D. R G Williams

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Abstract

The development of the PE/MAS 13C NMR spectrum of poly(d8MMA) cross-polarized by the protons of water is used to follow the distribution of water as it is absorbed by the polymer. In the early stages, water is in contact with the backbone CD2 and quaternary C. It makes contact with side-chain carbons later. A non-random distribution of close contacts between water and polymer molecules was also observed when P(d8 MMA) was precipitated from d8-acetone by water.

Original languageEnglish
Pages (from-to)359-362
Number of pages4
JournalPolymer Bulletin
Volume15
Issue number4
DOIs
Publication statusPublished - 1 Apr 1986
Externally publishedYes

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