The microwave spectrum and structure of Z-prop-2-ynylideneamine, HCCCHNH

D. McNaughton; O. I. Osman; H. W. Kroto

doi:10.1016/0022-2860(88)80284-9

The microwave spectrum and structure of Z-prop-2-ynylideneamine, HCCCHNH

D. McNaughton, O. I. Osman, H. W. Kroto

Research output: Contribution to journal › Article › Research › peer-review

10 Citations (Scopus)

Abstract

The microwave spectrum of Z-prop-2-ynylideneamine, HCCCHNH, has been measured between 26.5 and 40.0 GHz. The species has been made using a variety of techniques, the most convenient being the pyrolysis of dipropargylamine at 940°C. The detection of the three ¹³C isotopic species in natural abundance and two deuterated variants, DCCCHNH and HCCCHNH, has enabled a reliable partial substitution structure to be determined. Stark effect measurements have yielded μ_a = 2.145(2) debye and μ_b = 0.182(6) debye.

Original language	English
Pages (from-to)	195-204
Number of pages	10
Journal	Journal of Molecular Structure
Volume	190
Issue number	C
DOIs	https://doi.org/10.1016/0022-2860(88)80284-9
Publication status	Published - Nov 1988
Externally published	Yes

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title = "The microwave spectrum and structure of Z-prop-2-ynylideneamine, HCCCHNH",

abstract = "The microwave spectrum of Z-prop-2-ynylideneamine, HCCCHNH, has been measured between 26.5 and 40.0 GHz. The species has been made using a variety of techniques, the most convenient being the pyrolysis of dipropargylamine at 940°C. The detection of the three 13C isotopic species in natural abundance and two deuterated variants, DCCCHNH and HCCCHNH, has enabled a reliable partial substitution structure to be determined. Stark effect measurements have yielded μa = 2.145(2) debye and μb = 0.182(6) debye.",

author = "D. McNaughton and Osman, \{O. I.\} and Kroto, \{H. W.\}",

year = "1988",

month = nov,

doi = "10.1016/0022-2860(88)80284-9",

language = "English",

volume = "190",

pages = "195--204",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

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T1 - The microwave spectrum and structure of Z-prop-2-ynylideneamine, HCCCHNH

AU - McNaughton, D.

AU - Osman, O. I.

AU - Kroto, H. W.

PY - 1988/11

Y1 - 1988/11

N2 - The microwave spectrum of Z-prop-2-ynylideneamine, HCCCHNH, has been measured between 26.5 and 40.0 GHz. The species has been made using a variety of techniques, the most convenient being the pyrolysis of dipropargylamine at 940°C. The detection of the three 13C isotopic species in natural abundance and two deuterated variants, DCCCHNH and HCCCHNH, has enabled a reliable partial substitution structure to be determined. Stark effect measurements have yielded μa = 2.145(2) debye and μb = 0.182(6) debye.

AB - The microwave spectrum of Z-prop-2-ynylideneamine, HCCCHNH, has been measured between 26.5 and 40.0 GHz. The species has been made using a variety of techniques, the most convenient being the pyrolysis of dipropargylamine at 940°C. The detection of the three 13C isotopic species in natural abundance and two deuterated variants, DCCCHNH and HCCCHNH, has enabled a reliable partial substitution structure to be determined. Stark effect measurements have yielded μa = 2.145(2) debye and μb = 0.182(6) debye.

UR - https://www.scopus.com/pages/publications/45449124788

U2 - 10.1016/0022-2860(88)80284-9

DO - 10.1016/0022-2860(88)80284-9

M3 - Article

AN - SCOPUS:45449124788

SN - 0022-2860

VL - 190

SP - 195

EP - 204

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - C

ER -

The microwave spectrum and structure of Z-prop-2-ynylideneamine, HCCCHNH

Abstract

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