The microwave spectrum and structure of phosphaethene, ch2=ph

Ronald D. Brown; Peter D. Godfrey; Donald McNaughton

doi:10.1071/CH9810465

The microwave spectrum and structure of phosphaethene, ch₂=ph

Ronald D. Brown, Peter D. Godfrey, Donald McNaughton

School of Chemistry

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32 Citations (Scopus)

Abstract

The microwave spectra of phosphaethene (methylenephosphine) and five of its isotopic species have been observed and assigned in the region 5-125 GHz. Rotational constants and moments of inertia have been determined for ¹²CH₂PH, ¹³CH₂PH, ¹²CD₂PD, ¹²CD₂PH, (Z)^-12CHDPH and (E) ¹²CHDPH. The moments of inertia have been used to determine the following structural parameters: r_P-H= 1·425Å; r_C-P=l·671Å; r_c-H = 1·082 Å; ∠HCP_(Z) = 124·5°; ∠HCP_(E) = 119·1°; ∠CPH = 95.5°. The dipole moment components have been determined as j˜, = 0.7233(7) D and pb = O·4657(11) D.

Original language	English
Pages (from-to)	465-470
Number of pages	6
Journal	Australian Journal of Chemistry
Volume	34
Issue number	3
DOIs	https://doi.org/10.1071/CH9810465
Publication status	Published - 1981

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title = "The microwave spectrum and structure of phosphaethene, ch2=ph",

abstract = "The microwave spectra of phosphaethene (methylenephosphine) and five of its isotopic species have been observed and assigned in the region 5-125 GHz. Rotational constants and moments of inertia have been determined for 12CH2PH, 13CH2PH, 12CD2PD, 12CD2PH, (Z)-12CHDPH and (E) 12CHDPH. The moments of inertia have been used to determine the following structural parameters: rP-H= 1·425{\AA}; rC-P=l·671{\AA}; rc-H = 1·082 {\AA}; ∠HCP(Z) = 124·5°; ∠HCP(E) = 119·1°; ∠CPH = 95.5°. The dipole moment components have been determined as j˜, = 0.7233(7) D and pb = O·4657(11) D.",

author = "Brown, {Ronald D.} and Godfrey, {Peter D.} and Donald McNaughton",

year = "1981",

doi = "10.1071/CH9810465",

language = "English",

volume = "34",

pages = "465--470",

journal = "Australian Journal of Chemistry",

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T1 - The microwave spectrum and structure of phosphaethene, ch2=ph

AU - Brown, Ronald D.

AU - Godfrey, Peter D.

AU - McNaughton, Donald

PY - 1981

Y1 - 1981

N2 - The microwave spectra of phosphaethene (methylenephosphine) and five of its isotopic species have been observed and assigned in the region 5-125 GHz. Rotational constants and moments of inertia have been determined for 12CH2PH, 13CH2PH, 12CD2PD, 12CD2PH, (Z)-12CHDPH and (E) 12CHDPH. The moments of inertia have been used to determine the following structural parameters: rP-H= 1·425Å; rC-P=l·671Å; rc-H = 1·082 Å; ∠HCP(Z) = 124·5°; ∠HCP(E) = 119·1°; ∠CPH = 95.5°. The dipole moment components have been determined as j˜, = 0.7233(7) D and pb = O·4657(11) D.

AB - The microwave spectra of phosphaethene (methylenephosphine) and five of its isotopic species have been observed and assigned in the region 5-125 GHz. Rotational constants and moments of inertia have been determined for 12CH2PH, 13CH2PH, 12CD2PD, 12CD2PH, (Z)-12CHDPH and (E) 12CHDPH. The moments of inertia have been used to determine the following structural parameters: rP-H= 1·425Å; rC-P=l·671Å; rc-H = 1·082 Å; ∠HCP(Z) = 124·5°; ∠HCP(E) = 119·1°; ∠CPH = 95.5°. The dipole moment components have been determined as j˜, = 0.7233(7) D and pb = O·4657(11) D.

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VL - 34

SP - 465

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JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 3

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The microwave spectrum and structure of phosphaethene, ch2=ph

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The microwave spectrum and structure of phosphaethene, ch₂=ph