The inhibiting effects of cerium diphenyl phosphate on the corrosion and stress corrosion of 7075 aluminium alloy

F. Varela; J. Hill; M. Forsyth; N. Birbilis; P. Howlett; T. Markley; B. Hinton

The inhibiting effects of cerium diphenyl phosphate on the corrosion and stress corrosion of 7075 aluminium alloy

F. Varela
, J. Hill
, M. Forsyth
, N. Birbilis
, P. Howlett
, T. Markley
, B. Hinton

Materials Science & Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference Paper › Other

3 Citations (Scopus)

Abstract

This paper demonstrates the effectiveness of the compound cerium diphenyl phosphate (Ce(dpp) ₃) as a corrosion inhibitor. The results presented show that Ce(dpp) ₃ is an excellent inhibitor of pitting corrosion of aluminium alloy AA7075-T651 in a very aggressive environment of continuously aerated 0.1M sodium chloride (NaCl) solution. Polarisation studies indicate that in this solution, Ce(dpp) ₃ acts as a cathodic inhibitor by reducing the rate of the oxygen reduction reaction, which results in a decreased corrosion current density and a separation of the corrosion potential from the pitting potential. This inhibition is due to the formation of a complex surface film consisting of hydrolysed forms of Ce(dpp) ₃, cerium oxide, aluminium oxide and phosphate. A mechanism by which this film is formed is discussed. The paper also presents stress corrosion cracking (SCC) results, which show that Ce(dpp) ₃ can effectively delay the initiation of SCC and reduce the rate of cracking in NaCl solution.

Original language	English
Title of host publication	49th Annual Conference of the Australasian Corrosion Association 2009
Subtitle of host publication	Corrosion and Prevention 2009
Pages	804-814
Number of pages	11
Publication status	Published - 1 Dec 2009
Event	Australasian Corrosion Association (ACA) Conference 2009: Corrosion and Prevention - Coffs Harbour, Australia Duration: 15 Nov 2009 → 19 Nov 2009 Conference number: 49th

Publication series

Name	49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009

Conference

Conference	Australasian Corrosion Association (ACA) Conference 2009
Abbreviated title	CP 2009
Country/Territory	Australia
City	Coffs Harbour
Period	15/11/09 → 19/11/09

Keywords

Corrosion pitting
Inhibition
Stress corrosion cracking

Cite this

Varela, F., Hill, J., Forsyth, M., Birbilis, N., Howlett, P., Markley, T., & Hinton, B. (2009). The inhibiting effects of cerium diphenyl phosphate on the corrosion and stress corrosion of 7075 aluminium alloy. In 49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009 (pp. 804-814). (49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009).

Varela, F. ; Hill, J. ; Forsyth, M. et al. / The inhibiting effects of cerium diphenyl phosphate on the corrosion and stress corrosion of 7075 aluminium alloy. 49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009. 2009. pp. 804-814 (49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009).

@inproceedings{6ded4b75ea6d46408e075af2d188e4a0,

title = "The inhibiting effects of cerium diphenyl phosphate on the corrosion and stress corrosion of 7075 aluminium alloy",

abstract = "This paper demonstrates the effectiveness of the compound cerium diphenyl phosphate (Ce(dpp) 3) as a corrosion inhibitor. The results presented show that Ce(dpp) 3 is an excellent inhibitor of pitting corrosion of aluminium alloy AA7075-T651 in a very aggressive environment of continuously aerated 0.1M sodium chloride (NaCl) solution. Polarisation studies indicate that in this solution, Ce(dpp) 3 acts as a cathodic inhibitor by reducing the rate of the oxygen reduction reaction, which results in a decreased corrosion current density and a separation of the corrosion potential from the pitting potential. This inhibition is due to the formation of a complex surface film consisting of hydrolysed forms of Ce(dpp) 3, cerium oxide, aluminium oxide and phosphate. A mechanism by which this film is formed is discussed. The paper also presents stress corrosion cracking (SCC) results, which show that Ce(dpp) 3 can effectively delay the initiation of SCC and reduce the rate of cracking in NaCl solution.",

keywords = "Corrosion pitting, Inhibition, Stress corrosion cracking",

author = "F. Varela and J. Hill and M. Forsyth and N. Birbilis and P. Howlett and T. Markley and B. Hinton",

year = "2009",

month = dec,

day = "1",

language = "English",

isbn = "9781622762453",

series = "49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009",

pages = "804--814",

booktitle = "49th Annual Conference of the Australasian Corrosion Association 2009",

note = "Australasian Corrosion Association (ACA) Conference 2009 : Corrosion and Prevention, CP 2009 ; Conference date: 15-11-2009 Through 19-11-2009",

}

Varela, F, Hill, J, Forsyth, M, Birbilis, N, Howlett, P, Markley, T & Hinton, B 2009, The inhibiting effects of cerium diphenyl phosphate on the corrosion and stress corrosion of 7075 aluminium alloy. in 49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009. 49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009, pp. 804-814, Australasian Corrosion Association (ACA) Conference 2009, Coffs Harbour, New South Wales, Australia, 15/11/09.

The inhibiting effects of cerium diphenyl phosphate on the corrosion and stress corrosion of 7075 aluminium alloy. / Varela, F.; Hill, J.; Forsyth, M. et al.
49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009. 2009. p. 804-814 (49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009).

Research output: Chapter in Book/Report/Conference proceeding › Conference Paper › Other

TY - GEN

T1 - The inhibiting effects of cerium diphenyl phosphate on the corrosion and stress corrosion of 7075 aluminium alloy

AU - Varela, F.

AU - Hill, J.

AU - Forsyth, M.

AU - Birbilis, N.

AU - Howlett, P.

AU - Markley, T.

AU - Hinton, B.

N1 - Conference code: 49th

PY - 2009/12/1

Y1 - 2009/12/1

N2 - This paper demonstrates the effectiveness of the compound cerium diphenyl phosphate (Ce(dpp) 3) as a corrosion inhibitor. The results presented show that Ce(dpp) 3 is an excellent inhibitor of pitting corrosion of aluminium alloy AA7075-T651 in a very aggressive environment of continuously aerated 0.1M sodium chloride (NaCl) solution. Polarisation studies indicate that in this solution, Ce(dpp) 3 acts as a cathodic inhibitor by reducing the rate of the oxygen reduction reaction, which results in a decreased corrosion current density and a separation of the corrosion potential from the pitting potential. This inhibition is due to the formation of a complex surface film consisting of hydrolysed forms of Ce(dpp) 3, cerium oxide, aluminium oxide and phosphate. A mechanism by which this film is formed is discussed. The paper also presents stress corrosion cracking (SCC) results, which show that Ce(dpp) 3 can effectively delay the initiation of SCC and reduce the rate of cracking in NaCl solution.

AB - This paper demonstrates the effectiveness of the compound cerium diphenyl phosphate (Ce(dpp) 3) as a corrosion inhibitor. The results presented show that Ce(dpp) 3 is an excellent inhibitor of pitting corrosion of aluminium alloy AA7075-T651 in a very aggressive environment of continuously aerated 0.1M sodium chloride (NaCl) solution. Polarisation studies indicate that in this solution, Ce(dpp) 3 acts as a cathodic inhibitor by reducing the rate of the oxygen reduction reaction, which results in a decreased corrosion current density and a separation of the corrosion potential from the pitting potential. This inhibition is due to the formation of a complex surface film consisting of hydrolysed forms of Ce(dpp) 3, cerium oxide, aluminium oxide and phosphate. A mechanism by which this film is formed is discussed. The paper also presents stress corrosion cracking (SCC) results, which show that Ce(dpp) 3 can effectively delay the initiation of SCC and reduce the rate of cracking in NaCl solution.

KW - Corrosion pitting

KW - Inhibition

KW - Stress corrosion cracking

UR - https://www.scopus.com/pages/publications/84867754010

M3 - Conference Paper

AN - SCOPUS:84867754010

SN - 9781622762453

T3 - 49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009

SP - 804

EP - 814

BT - 49th Annual Conference of the Australasian Corrosion Association 2009

T2 - Australasian Corrosion Association (ACA) Conference 2009

Y2 - 15 November 2009 through 19 November 2009

ER -

Varela F, Hill J, Forsyth M, Birbilis N, Howlett P, Markley T et al. The inhibiting effects of cerium diphenyl phosphate on the corrosion and stress corrosion of 7075 aluminium alloy. In 49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009. 2009. p. 804-814. (49th Annual Conference of the Australasian Corrosion Association 2009: Corrosion and Prevention 2009).

The inhibiting effects of cerium diphenyl phosphate on the corrosion and stress corrosion of 7075 aluminium alloy

Abstract

Publication series

Conference

Keywords

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Cite this