The influence of anion chemistry on the ionic conductivity and molecular dynamics in protic organic ionic plastic crystals

Jun Rao, R. Vijayaraghavan, Yundong Zhou, Patrick C. Howlett, Douglas R. Macfarlane, Maria Forsyth, Haijin Zhu

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Proton conductors are widely used in different electrochemical devices including fuel cells and redox flow batteries. Compared to conventional proton conducting polymer membranes, protic organic ionic plastic crystal (POIPC) is a novel solid-state proton conductor with high proton conductivity even under anhydrous conditions. In this work, different organic protic salts based on the same parent di-functional cation with different anions were synthesized and characterized. It is found that the di-protonated cation plays an important role in defining the thermal properties, leading to stronger plastic crystal behavior and a higher melting point. Static solid-state NMR and the synchrotron XRD results show that the di-protonated cation allows greater dynamics in the crystal in contrast to the mono-protonated counterparts. The 1-(N,N-dimethylammonium)-2-(ammonium)ethane triflate ([DMEDAH2][Tf]2) has the highest ionic conductivity of 1.1 × 10-4 S cm-1 at 50 °C, whereas the bis(trifluoromethanesulfonyl)amide counterpart [DMEDAH2][TFSA]2 has the lowest ionic conductivity (2.8 × 10-7 S cm-1 at 50 °C) with no measureable mobile ion component at this temperature. The fraction of mobile species is significantly suppressed in the TFSA containing salts as against the Tf systems.

Original languageEnglish
Pages (from-to)4579-4586
Number of pages8
JournalPhysical Chemistry Chemical Physics
Volume20
Issue number6
DOIs
Publication statusPublished - 2018

Cite this

Rao, Jun ; Vijayaraghavan, R. ; Zhou, Yundong ; Howlett, Patrick C. ; Macfarlane, Douglas R. ; Forsyth, Maria ; Zhu, Haijin. / The influence of anion chemistry on the ionic conductivity and molecular dynamics in protic organic ionic plastic crystals. In: Physical Chemistry Chemical Physics. 2018 ; Vol. 20, No. 6. pp. 4579-4586.
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abstract = "Proton conductors are widely used in different electrochemical devices including fuel cells and redox flow batteries. Compared to conventional proton conducting polymer membranes, protic organic ionic plastic crystal (POIPC) is a novel solid-state proton conductor with high proton conductivity even under anhydrous conditions. In this work, different organic protic salts based on the same parent di-functional cation with different anions were synthesized and characterized. It is found that the di-protonated cation plays an important role in defining the thermal properties, leading to stronger plastic crystal behavior and a higher melting point. Static solid-state NMR and the synchrotron XRD results show that the di-protonated cation allows greater dynamics in the crystal in contrast to the mono-protonated counterparts. The 1-(N,N-dimethylammonium)-2-(ammonium)ethane triflate ([DMEDAH2][Tf]2) has the highest ionic conductivity of 1.1 × 10-4 S cm-1 at 50 °C, whereas the bis(trifluoromethanesulfonyl)amide counterpart [DMEDAH2][TFSA]2 has the lowest ionic conductivity (2.8 × 10-7 S cm-1 at 50 °C) with no measureable mobile ion component at this temperature. The fraction of mobile species is significantly suppressed in the TFSA containing salts as against the Tf systems.",
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The influence of anion chemistry on the ionic conductivity and molecular dynamics in protic organic ionic plastic crystals. / Rao, Jun; Vijayaraghavan, R.; Zhou, Yundong; Howlett, Patrick C.; Macfarlane, Douglas R.; Forsyth, Maria; Zhu, Haijin.

In: Physical Chemistry Chemical Physics, Vol. 20, No. 6, 2018, p. 4579-4586.

Research output: Contribution to journalArticleResearchpeer-review

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