The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates

Athina Anastasaki; Christopher Waldron; Paul Wilson; Ronan McHale; David M. Haddleton

doi:10.1039/c3py00270e

The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates

Athina Anastasaki
, Christopher Waldron
, Paul Wilson
, Ronan McHale
, David M. Haddleton

Research output: Contribution to journal › Article › Research › peer-review

67 Citations (Scopus)

Abstract

Ligand mediated termination events occur during the homo-polymerisation of methyl (MA) and butyl (BA) acrylate under SET-LRP (Cu(0) mediated) conditions. Careful optimization of [initiator]/[ligand] (Me₆Tren) ratios is required to reduce termination in order to achieve optimum polymerisation.

Original language	English
Pages (from-to)	2672-2675
Number of pages	4
Journal	Polymer Chemistry
Volume	4
Issue number	9
DOIs	https://doi.org/10.1039/c3py00270e
Publication status	Published - 7 May 2013
Externally published	Yes

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title = "The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates",

abstract = "Ligand mediated termination events occur during the homo-polymerisation of methyl (MA) and butyl (BA) acrylate under SET-LRP (Cu(0) mediated) conditions. Careful optimization of [initiator]/[ligand] (Me6Tren) ratios is required to reduce termination in order to achieve optimum polymerisation.",

author = "Athina Anastasaki and Christopher Waldron and Paul Wilson and Ronan McHale and Haddleton, \{David M.\}",

year = "2013",

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AU - Anastasaki, Athina

AU - Waldron, Christopher

AU - Wilson, Paul

AU - McHale, Ronan

AU - Haddleton, David M.

PY - 2013/5/7

Y1 - 2013/5/7

N2 - Ligand mediated termination events occur during the homo-polymerisation of methyl (MA) and butyl (BA) acrylate under SET-LRP (Cu(0) mediated) conditions. Careful optimization of [initiator]/[ligand] (Me6Tren) ratios is required to reduce termination in order to achieve optimum polymerisation.

AB - Ligand mediated termination events occur during the homo-polymerisation of methyl (MA) and butyl (BA) acrylate under SET-LRP (Cu(0) mediated) conditions. Careful optimization of [initiator]/[ligand] (Me6Tren) ratios is required to reduce termination in order to achieve optimum polymerisation.

UR - https://www.scopus.com/pages/publications/84875836069

U2 - 10.1039/c3py00270e

DO - 10.1039/c3py00270e

M3 - Article

AN - SCOPUS:84875836069

SN - 1759-9954

VL - 4

SP - 2672

EP - 2675

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 9

ER -

The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates

Abstract

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