The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres

Chris Ritchie; Chloë E. Miller; Colette Boskovic

doi:10.1039/c1dt10866b

The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres

Chris Ritchie, Chloë E. Miller, Colette Boskovic

Research output: Contribution to journal › Article › Research › peer-review

26 Citations (Scopus)

Abstract

A new polyoxometalate-based 3D framework K₅Na[K ₂{Dy(H₂O)₃}₂{As₂W ₁₉O₆₈}{WO₂(pic)}₂] (1) (pic = 2-picolinate), composed of picolinate-functionalised dysprosium-containing tungstoarsenates and distorted potassium-picolinate cubane units, has been synthesised from the polyoxometalate precursor [As₂W ₁₉O₆₇(H₂O)]^14-.

Original language	English
Pages (from-to)	12037-12039
Number of pages	3
Journal	Dalton Transactions
Volume	40
Issue number	45
DOIs	https://doi.org/10.1039/c1dt10866b
Publication status	Published - 7 Dec 2011
Externally published	Yes

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abstract = "A new polyoxometalate-based 3D framework K5Na[K 2{Dy(H2O)3}2{As2W 19O68}{WO2(pic)}2] (1) (pic = 2-picolinate), composed of picolinate-functionalised dysprosium-containing tungstoarsenates and distorted potassium-picolinate cubane units, has been synthesised from the polyoxometalate precursor [As2W 19O67(H2O)]14-.",

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The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres

Abstract

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