The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres

Chris Ritchie, Chloë E. Miller, Colette Boskovic

Research output: Contribution to journalArticleResearchpeer-review

21 Citations (Scopus)

Abstract

A new polyoxometalate-based 3D framework K5Na[K 2{Dy(H2O)3}2{As2W 19O68}{WO2(pic)}2] (1) (pic = 2-picolinate), composed of picolinate-functionalised dysprosium-containing tungstoarsenates and distorted potassium-picolinate cubane units, has been synthesised from the polyoxometalate precursor [As2W 19O67(H2O)]14-.

Original languageEnglish
Pages (from-to)12037-12039
Number of pages3
JournalDalton Transactions
Volume40
Issue number45
DOIs
Publication statusPublished - 7 Dec 2011
Externally publishedYes

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