TY - JOUR
T1 - The generation and microwave spectrum of propadienethione, H 2C=C=C=S
AU - Brown, Ronald D.
AU - Godfrey, Peter D.
AU - Elmes, Patricia S.
AU - McNaughton, Donald
PY - 1987/12/1
Y1 - 1987/12/1
N2 - The third member of the cumulenethione series, H2CnS, propadienethione, has been produced by pyrolysis of cyclopenteno-1,2,3- thiadiazole and detected by microwave spectroscopy which provided rotational parameters for the 32S and 34S isotopomers, the dipole moment [2.064(8) Debye], and an indication that propadienethione is a planar molecule of C2v symmetry.
AB - The third member of the cumulenethione series, H2CnS, propadienethione, has been produced by pyrolysis of cyclopenteno-1,2,3- thiadiazole and detected by microwave spectroscopy which provided rotational parameters for the 32S and 34S isotopomers, the dipole moment [2.064(8) Debye], and an indication that propadienethione is a planar molecule of C2v symmetry.
UR - http://www.scopus.com/inward/record.url?scp=37049084795&partnerID=8YFLogxK
U2 - 10.1039/C39870000573
DO - 10.1039/C39870000573
M3 - Article
AN - SCOPUS:37049084795
SN - 0022-4936
SP - 573
EP - 574
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 8
ER -