The formation of organometallic compounds by sulphur dioxide elimination reactions of the pentafluorobenzenesulphinate ion

R. J. Bertino, P. G. Cookson, G. B. Deacon, I. K. Johnson

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Abstract

Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C6F5SO2Fe(π-C5H5)(CO)2 gives C6F5Fe(π-C5H5)(CO)21, and a pentaflurophenyliridium compound has been prepared by the reaction2:. IrCl(Ph3P)2N2 + C6F5SO2Cl→ C6F5IrCl2(Ph3P)2SO2 + N2 (1).

Original languageEnglish
Pages (from-to)122-124
Number of pages3
JournalJournal of Fluorine Chemistry
Volume3
Issue number1
DOIs
Publication statusPublished - 1 Jan 1973

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