Abstract
Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C6F5SO2Fe(π-C5H5)(CO)2 gives C6F5Fe(π-C5H5)(CO)21, and a pentaflurophenyliridium compound has been prepared by the reaction2:. IrCl(Ph3P)2N2 + C6F5SO2Cl→ C6F5IrCl2(Ph3P)2SO2 + N2 (1).
| Original language | English |
|---|---|
| Pages (from-to) | 122-124 |
| Number of pages | 3 |
| Journal | Journal of Fluorine Chemistry |
| Volume | 3 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1 Jan 1973 |
Cite this
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The formation of organometallic compounds by sulphur dioxide elimination reactions of the pentafluorobenzenesulphinate ion. / Bertino, R. J.; Cookson, P. G.; Deacon, G. B.; Johnson, I. K.
In: Journal of Fluorine Chemistry, Vol. 3, No. 1, 01.01.1973, p. 122-124.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - The formation of organometallic compounds by sulphur dioxide elimination reactions of the pentafluorobenzenesulphinate ion
AU - Bertino, R. J.
AU - Cookson, P. G.
AU - Deacon, G. B.
AU - Johnson, I. K.
PY - 1973/1/1
Y1 - 1973/1/1
N2 - Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C6F5SO2Fe(π-C5H5)(CO)2 gives C6F5Fe(π-C5H5)(CO)21, and a pentaflurophenyliridium compound has been prepared by the reaction2:. IrCl(Ph3P)2N2 + C6F5SO2Cl→ C6F5IrCl2(Ph3P)2SO2 + N2 (1).
AB - Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C6F5SO2Fe(π-C5H5)(CO)2 gives C6F5Fe(π-C5H5)(CO)21, and a pentaflurophenyliridium compound has been prepared by the reaction2:. IrCl(Ph3P)2N2 + C6F5SO2Cl→ C6F5IrCl2(Ph3P)2SO2 + N2 (1).
UR - http://www.scopus.com/inward/record.url?scp=49549164170&partnerID=8YFLogxK
U2 - 10.1016/S0022-1139(00)82867-5
DO - 10.1016/S0022-1139(00)82867-5
M3 - Article
VL - 3
SP - 122
EP - 124
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
SN - 0022-1139
IS - 1
ER -