The formation of organometallic compounds by sulphur dioxide elimination reactions of the pentafluorobenzenesulphinate ion

R. J. Bertino; P. G. Cookson; G. B. Deacon; I. K. Johnson

doi:10.1016/S0022-1139(00)82867-5

The formation of organometallic compounds by sulphur dioxide elimination reactions of the pentafluorobenzenesulphinate ion

R. J. Bertino, P. G. Cookson, G. B. Deacon, I. K. Johnson

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

7 Citations (Scopus)

Abstract

Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C₆F₅SO₂Fe(π-C₅H₅)(CO)₂ gives C₆F₅Fe(π-C₅H₅)(CO)₂¹, and a pentaflurophenyliridium compound has been prepared by the reaction²:. IrCl(Ph₃P)₂N₂ + C₆F₅SO₂Cl→ C₆F₅IrCl₂(Ph₃P)₂SO₂ + N₂ (1).

Original language	English
Pages (from-to)	122-124
Number of pages	3
Journal	Journal of Fluorine Chemistry
Volume	3
Issue number	1
DOIs	https://doi.org/10.1016/S0022-1139(00)82867-5
Publication status	Published - 1 Jan 1973

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10.1016/S0022-1139(00)82867-5

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title = "The formation of organometallic compounds by sulphur dioxide elimination reactions of the pentafluorobenzenesulphinate ion",

abstract = "Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C6F5SO2Fe(π-C5H5)(CO)2 gives C6F5Fe(π-C5H5)(CO)21, and a pentaflurophenyliridium compound has been prepared by the reaction2:. IrCl(Ph3P)2N2 + C6F5SO2Cl→ C6F5IrCl2(Ph3P)2SO2 + N2 (1).",

author = "Bertino, {R. J.} and Cookson, {P. G.} and Deacon, {G. B.} and Johnson, {I. K.}",

year = "1973",

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doi = "10.1016/S0022-1139(00)82867-5",

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journal = "Journal of Fluorine Chemistry",

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T1 - The formation of organometallic compounds by sulphur dioxide elimination reactions of the pentafluorobenzenesulphinate ion

AU - Bertino, R. J.

AU - Cookson, P. G.

AU - Deacon, G. B.

AU - Johnson, I. K.

PY - 1973/1/1

Y1 - 1973/1/1

N2 - Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C6F5SO2Fe(π-C5H5)(CO)2 gives C6F5Fe(π-C5H5)(CO)21, and a pentaflurophenyliridium compound has been prepared by the reaction2:. IrCl(Ph3P)2N2 + C6F5SO2Cl→ C6F5IrCl2(Ph3P)2SO2 + N2 (1).

AB - Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C6F5SO2Fe(π-C5H5)(CO)2 gives C6F5Fe(π-C5H5)(CO)21, and a pentaflurophenyliridium compound has been prepared by the reaction2:. IrCl(Ph3P)2N2 + C6F5SO2Cl→ C6F5IrCl2(Ph3P)2SO2 + N2 (1).

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U2 - 10.1016/S0022-1139(00)82867-5

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JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

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