The formation of organometallic compounds by sulphur dioxide elimination reactions of the pentafluorobenzenesulphinate ion

R. J. Bertino, P. G. Cookson, G. B. Deacon, I. K. Johnson

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7 Citations (Scopus)

Abstract

Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C6F5SO2Fe(π-C5H5)(CO)2 gives C6F5Fe(π-C5H5)(CO)21, and a pentaflurophenyliridium compound has been prepared by the reaction2:. IrCl(Ph3P)2N2 + C6F5SO2Cl→ C6F5IrCl2(Ph3P)2SO2 + N2 (1).

Original languageEnglish
Pages (from-to)122-124
Number of pages3
JournalJournal of Fluorine Chemistry
Volume3
Issue number1
DOIs
Publication statusPublished - 1 Jan 1973

Cite this

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title = "The formation of organometallic compounds by sulphur dioxide elimination reactions of the pentafluorobenzenesulphinate ion",
abstract = "Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C6F5SO2Fe(π-C5H5)(CO)2 gives C6F5Fe(π-C5H5)(CO)21, and a pentaflurophenyliridium compound has been prepared by the reaction2:. IrCl(Ph3P)2N2 + C6F5SO2Cl→ C6F5IrCl2(Ph3P)2SO2 + N2 (1).",
author = "Bertino, {R. J.} and Cookson, {P. G.} and Deacon, {G. B.} and Johnson, {I. K.}",
year = "1973",
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The formation of organometallic compounds by sulphur dioxide elimination reactions of the pentafluorobenzenesulphinate ion. / Bertino, R. J.; Cookson, P. G.; Deacon, G. B.; Johnson, I. K.

In: Journal of Fluorine Chemistry, Vol. 3, No. 1, 01.01.1973, p. 122-124.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - The formation of organometallic compounds by sulphur dioxide elimination reactions of the pentafluorobenzenesulphinate ion

AU - Bertino, R. J.

AU - Cookson, P. G.

AU - Deacon, G. B.

AU - Johnson, I. K.

PY - 1973/1/1

Y1 - 1973/1/1

N2 - Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C6F5SO2Fe(π-C5H5)(CO)2 gives C6F5Fe(π-C5H5)(CO)21, and a pentaflurophenyliridium compound has been prepared by the reaction2:. IrCl(Ph3P)2N2 + C6F5SO2Cl→ C6F5IrCl2(Ph3P)2SO2 + N2 (1).

AB - Only two preparations of pentafluorophenylorganometallics by sulphur dioxide elimination reactions have been reported. Thermal decomposition of the S-sulphinato complex C6F5SO2Fe(π-C5H5)(CO)2 gives C6F5Fe(π-C5H5)(CO)21, and a pentaflurophenyliridium compound has been prepared by the reaction2:. IrCl(Ph3P)2N2 + C6F5SO2Cl→ C6F5IrCl2(Ph3P)2SO2 + N2 (1).

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DO - 10.1016/S0022-1139(00)82867-5

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EP - 124

JO - Journal of Fluorine Chemistry

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