The first complexes and cyclodimerisations of methylphosphaalkyne (P≡CMe)

Cameron Jones; Christian Schulten; Andreas Stasch

doi:10.1039/b607489h

The first complexes and cyclodimerisations of methylphosphaalkyne (P≡CMe)

Cameron Jones, Christian Schulten, Andreas Stasch

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

12 Citations (Scopus)

Abstract

The first complexes and cyclodimerisations of methylphosphaalkyne, P≡CMe, are reported to arise from its reactions with a range of platinum(0) complexes and [W(CO)₅(THF)]. A number of differences between the chemistry of this phosphaalkyne and that of its bulkier analogues have been highlighted and explained on steric grounds.

Original language	English
Pages (from-to)	3733-3735
Number of pages	3
Journal	Dalton Transactions
Issue number	31
DOIs	https://doi.org/10.1039/b607489h
Publication status	Published - 1 Aug 2006

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abstract = "The first complexes and cyclodimerisations of methylphosphaalkyne, P≡CMe, are reported to arise from its reactions with a range of platinum(0) complexes and [W(CO)5(THF)]. A number of differences between the chemistry of this phosphaalkyne and that of its bulkier analogues have been highlighted and explained on steric grounds.",

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AB - The first complexes and cyclodimerisations of methylphosphaalkyne, P≡CMe, are reported to arise from its reactions with a range of platinum(0) complexes and [W(CO)5(THF)]. A number of differences between the chemistry of this phosphaalkyne and that of its bulkier analogues have been highlighted and explained on steric grounds.

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JO - Dalton Transactions

JF - Dalton Transactions

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The first complexes and cyclodimerisations of methylphosphaalkyne (P≡CMe)

Abstract

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